{"doi":"10.1557/jmr.1999.0576","title":"Effect of substituents with different valences on antiferroelectric stability of antiferroelectric lead zirconate ceramics","abstract":"<jats:p>The effect of lower valent substituents on the stability of the antiferroelectric phase of lead zirconate was studied by dielectric spectroscopy, Sawyer–Tower polarization methods, and electron diffraction techniques. The stability of an intermediate ferroelectric phase region was found to be enhanced with increasing lower valent substitution concentration. The influences of substituents of different ionic size and valence on the stabilization of the intermediate ferroelectric phase were differentiated. In general, lower valent substituents, such as K<jats:sup>+</jats:sup> and Fe<jats:sup>3+</jats:sup> affected antiferroelectric phase stability more significantly than higher valent ones.</jats:p>","journal":"Journal of Materials Research","year":1999,"id":684496,"datarank":0.4335557636844247,"base_score":2.8903717578961645,"endowment":2.8903717578961645,"self_citation_contribution":0.4335557636844247,"citation_network_contribution":0.0,"self_endowment_contribution":0.4335557636844247,"citer_contribution":0.0,"corpus_percentile":null,"corpus_rank":null,"citation_count":17,"citer_count":0,"citers_with_citation_signal":0,"citers_with_endowment":0,"datacite_reuse_total":0,"is_dataset":false,"is_dataset_confidence":null,"is_data_producer":false,"deposit_databanks":null,"is_oa":false,"file_count":0,"downloads":0,"has_version_chain":false,"published_date":null,"fair_score":null,"fair_percentile":null,"algorithm_id":"datarank_citation_only_1hop_v6","ranking_scope":"data_only","authors":[{"id":1470182,"name":"Z. Xu","orcid":"0000-0002-7465-8513","position":1,"is_corresponding":false},{"id":1788253,"name":"Dwight Viehland","orcid":null,"position":2,"is_corresponding":false},{"id":493391,"name":"Qi Tan","orcid":"0000-0002-5756-4101","position":0,"is_corresponding":false}],"reference_count":0,"raw_metadata":{"has_enrichment":true,"resolved":true,"title":"Effect of substituents with different valences on antiferroelectric stability of antiferroelectric lead zirconate ceramics","abstract":"<jats:p>The effect of lower valent substituents on the stability of the antiferroelectric phase of lead zirconate was studied by dielectric spectroscopy, Sawyer–Tower polarization methods, and electron diffraction techniques. The stability of an intermediate ferroelectric phase region was found to be enhanced with increasing lower valent substitution concentration. The influences of substituents of different ionic size and valence on the stabilization of the intermediate ferroelectric phase were differentiated. In general, lower valent substituents, such as K<jats:sup>+</jats:sup> and Fe<jats:sup>3+</jats:sup> affected antiferroelectric phase stability more significantly than higher valent ones.</jats:p>","is_dataset_classified":null,"base_score":2.8903717578961645,"endowment":2.8903717578961645,"datacite_reuse_total":0,"file_count":0,"downloads":0,"views":0,"has_version_chain":false,"is_dataset":false,"is_oa":false,"pmid":"26207759","pmcid":null,"openalex_id":"https://openalex.org/W2165972729","authors":[],"funders":[],"total_grants":0,"fwci":0.0,"citation_percentile":0.18024362,"influential_citations":0,"citation_trend":[{"year":2012,"count":1},{"year":2013,"count":2},{"year":2014,"count":3},{"year":2015,"count":1},{"year":2016,"count":2},{"year":2018,"count":1},{"year":2021,"count":3}],"oa_status":"closed","license":"https://www.cambridge.org/core/terms","oa_locations":[{"url":"https://www.cambridge.org/core/services/aop-cambridge-core/content/view/S0884291400052791","host_type":"publisher"},{"url":"https://doi.org/10.1557/jmr.1999.0576","host_type":"journal"}],"fields_of_study":["Ferroelectric and Piezoelectric Materials","Multiferroics and related materials","Microwave Dielectric Ceramics Synthesis"],"mesh_terms":[],"keywords":["Antiferroelectricity","Materials science","Ferroelectricity","Zirconate","Valence (chemistry)","Dielectric","Phase (matter)","Ceramic","Ionic bonding","Polarization (electrochemistry)","Crystallography","Physical chemistry","Ion","Composite material","Organic chemistry","Chemistry","Titanate","Optoelectronics"],"sdg_mappings":[],"linked_datasets":[],"clinical_trials":[],"software_tools":[],"database_accessions":[],"source":"live","citation_network_status":"fetched"},"created_at":"2026-08-18T14:16:05.829926Z","pmid":null,"pmcid":null,"fwci":null,"citation_percentile":null,"influential_citations":0,"oa_status":null,"license":null,"views":0,"total_file_size_bytes":0,"version_count":0,"fair_f":null,"fair_a":null,"fair_i":null,"fair_r":null,"fair_zscore":null,"fair_rationale":null,"fair_model":null,"fair_agent_version":null,"fair_fulltext_source":null,"fair_has_llm":null,"fair_computed_at":null,"clinical_trials":[],"software_tools":[],"db_accessions":[],"linked_datasets":[],"topics":[]}