{"doi":"10.1246/bcsj.62.23","title":"The Synthesis and Oxidation of Mixed Cobalt(III) Complexes with Dimethyldithiocarbamato and Diamine Ligands, and the Crystal Structure of (+)500CD-Dimethyldithiocarbamatobis(ethylenediamine)cobalt(III) Bis[μ-(<i>R</i>,<i>R</i>)-tartrato]dianxtimonate(III) Pentahydrate","abstract":"<jats:title>Abstract</jats:title>\n               <jats:p>Dithiocarbamato complexes, [Co(dtc)3−n(diamine)n]n+ (n=1 and 2 and dtc=dimethyldithiocarbamate) were newly prepared and characterized by means of their absorption, CD, and MCD spectra. (+)500CD-[Co(dtc)(en)2][Sb2(R,R-C4H2O6)2]·5H2O crystallized in the monoclinic space group of P21 with a=14.630(3), b=9.300(1), c=12.023(5) Å, β=110.78(3)°, V=1529.4(8) Å3, and Z=2. The refinement of 3346 reflections (Mo Kα radiation) led to R=0.073. The dtc complex had a Λ configuration. The Co–N bond trans to the dtc sulfur atom was longer by 0.026 A than the cis one. A novel oxidation derivative, [Co{(dimethylamino)thioxomethanesulfinato-O,S}(en)2]2+, was prepared and characterized by means of its XPS spectrum.</jats:p>","journal":"Bulletin of the Chemical Society of Japan","year":1989,"id":685883,"datarank":0.40620753016533157,"base_score":2.70805020110221,"endowment":2.70805020110221,"self_citation_contribution":0.40620753016533157,"citation_network_contribution":0.0,"self_endowment_contribution":0.40620753016533157,"citer_contribution":0.0,"corpus_percentile":null,"corpus_rank":null,"citation_count":14,"citer_count":0,"citers_with_citation_signal":0,"citers_with_endowment":0,"datacite_reuse_total":0,"is_dataset":false,"is_dataset_confidence":null,"is_data_producer":false,"deposit_databanks":null,"is_oa":false,"file_count":0,"downloads":0,"has_version_chain":false,"published_date":null,"fair_score":null,"fair_percentile":null,"algorithm_id":"datarank_citation_only_1hop_v6","ranking_scope":"data_only","authors":[{"id":1787452,"name":"Kazuaki Yamanari","orcid":null,"position":1,"is_corresponding":false},{"id":1787453,"name":"Yoichi Shimura","orcid":null,"position":2,"is_corresponding":false},{"id":1791950,"name":"Masakazu Kita","orcid":null,"position":0,"is_corresponding":false}],"reference_count":0,"raw_metadata":{"has_enrichment":true,"resolved":true,"title":"The Synthesis and Oxidation of Mixed Cobalt(III) Complexes with Dimethyldithiocarbamato and Diamine Ligands, and the Crystal Structure of (+)500CD-Dimethyldithiocarbamatobis(ethylenediamine)cobalt(III) Bis[μ-(<i>R</i>,<i>R</i>)-tartrato]dianxtimonate(III) Pentahydrate","abstract":"<jats:title>Abstract</jats:title>\n               <jats:p>Dithiocarbamato complexes, [Co(dtc)3−n(diamine)n]n+ (n=1 and 2 and dtc=dimethyldithiocarbamate) were newly prepared and characterized by means of their absorption, CD, and MCD spectra. (+)500CD-[Co(dtc)(en)2][Sb2(R,R-C4H2O6)2]·5H2O crystallized in the monoclinic space group of P21 with a=14.630(3), b=9.300(1), c=12.023(5) Å, β=110.78(3)°, V=1529.4(8) Å3, and Z=2. The refinement of 3346 reflections (Mo Kα radiation) led to R=0.073. The dtc complex had a Λ configuration. The Co–N bond trans to the dtc sulfur atom was longer by 0.026 A than the cis one. A novel oxidation derivative, [Co{(dimethylamino)thioxomethanesulfinato-O,S}(en)2]2+, was prepared and characterized by means of its XPS spectrum.</jats:p>","is_dataset_classified":null,"base_score":2.70805020110221,"endowment":2.70805020110221,"datacite_reuse_total":0,"file_count":0,"downloads":0,"views":0,"has_version_chain":false,"is_dataset":false,"is_oa":false,"pmid":null,"pmcid":null,"openalex_id":"https://openalex.org/W2053357505","authors":[],"funders":[],"total_grants":0,"fwci":1.4907,"citation_percentile":0.7806092,"influential_citations":0,"citation_trend":[{"year":2012,"count":1},{"year":2013,"count":1}],"oa_status":"closed","license":"https://academic.oup.com/pages/standard-publication-reuse-rights","oa_locations":[{"url":"https://academic.oup.com/bcsj/article-pdf/62/1/23/55727165/bcsj.62.23.pdf","host_type":"publisher"},{"url":"https://doi.org/10.1246/bcsj.62.23","host_type":"journal"}],"fields_of_study":["Organometallic Compounds Synthesis and Characterization","Metal complexes synthesis and properties","Crystal structures of chemical compounds"],"mesh_terms":[],"keywords":["Chemistry","Ethylenediamine","Cobalt","Diamine","Crystal structure","Inorganic chemistry","Crystallography","Polymer chemistry"],"sdg_mappings":[{"sdg_number":0,"sdg_label":"Clean water and sanitation"}],"linked_datasets":[],"clinical_trials":[],"software_tools":[],"database_accessions":[],"source":"live","citation_network_status":"fetched"},"created_at":"2026-08-18T17:57:10.331178Z","pmid":null,"pmcid":null,"fwci":null,"citation_percentile":null,"influential_citations":0,"oa_status":null,"license":null,"views":0,"total_file_size_bytes":0,"version_count":0,"fair_f":null,"fair_a":null,"fair_i":null,"fair_r":null,"fair_zscore":null,"fair_rationale":null,"fair_model":null,"fair_agent_version":null,"fair_fulltext_source":null,"fair_has_llm":null,"fair_computed_at":null,"clinical_trials":[],"software_tools":[],"db_accessions":[],"linked_datasets":[],"topics":[]}