{"doi":"10.1246/bcsj.50.3302","title":"The Reaction of <i>N</i>-Imidoylsulfimides with Carbon Disulfide","abstract":"<jats:title>Abstract</jats:title>\n               <jats:p>The reaction of S,S-diphenyl- and S,S-dimethyl-N-imidoylsulfimides (1 and 2) with carbon disulfide was studied. 1 yielded nitrile, isothiocyanate, diphenyl sulfide, and sulfur, whereas 2 gave N-thiocarbonyl-S,S-dimethylsulfimide together with isothiocyanate. Kinetic studies indicate that the reaction proceeds via a [2+2]cycloaddition mechnism, as is shown by the small effects of the solvents and the substitutent on the rate.</jats:p>","journal":"Bulletin of the Chemical Society of Japan","year":1977,"id":21698,"datarank":0.6225506246962896,"base_score":1.9459101490553132,"endowment":1.9459101490553132,"self_citation_contribution":0.29188652235829704,"citation_network_contribution":0.3306641023379926,"self_endowment_contribution":0.29188652235829704,"citer_contribution":0.3306641023379926,"corpus_percentile":null,"corpus_rank":null,"citation_count":6,"citer_count":5,"citers_with_citation_signal":5,"citers_with_endowment":5,"datacite_reuse_total":0,"is_dataset":false,"is_dataset_confidence":null,"is_data_producer":false,"deposit_databanks":null,"is_oa":false,"file_count":0,"downloads":0,"has_version_chain":false,"published_date":null,"fair_score":null,"fair_percentile":null,"algorithm_id":"datarank_citation_only_1hop_v6","ranking_scope":"data_only","authors":[{"id":138789,"name":"Tsuyoshi Ogata","orcid":null,"position":1,"is_corresponding":false},{"id":138790,"name":"Saburo Inokawa","orcid":null,"position":2,"is_corresponding":false},{"id":36135,"name":"Hiroshi Yoshida","orcid":null,"position":0,"is_corresponding":false}],"reference_count":0,"raw_metadata":{"has_enrichment":true,"base_score":1.9459101490553132,"endowment":1.9459101490553132,"datacite_reuse_total":0,"file_count":0,"downloads":0,"views":0,"has_version_chain":false,"is_dataset":false,"is_oa":false,"pmid":"21071399","pmcid":null,"openalex_id":"https://openalex.org/W2042901775","authors":[],"funders":[],"total_grants":0,"fwci":0.6164,"citation_percentile":0.6412716,"influential_citations":0,"citation_trend":[],"oa_status":"closed","license":"https://academic.oup.com/pages/standard-publication-reuse-rights","oa_locations":[{"url":"https://academic.oup.com/bcsj/article-pdf/50/12/3302/56095284/bcsj.50.3302.pdf","host_type":"publisher"},{"url":"https://doi.org/10.1246/bcsj.50.3302","host_type":"journal"}],"fields_of_study":["Sulfur-Based Synthesis Techniques","Synthesis and Reactivity of Sulfur-Containing Compounds","Synthesis and Catalytic Reactions","Chemistry"],"mesh_terms":[],"keywords":["Chemistry","Carbon disulfide","Disulfide bond","Carbon fibers","Medicinal chemistry","Organic chemistry","Biochemistry"],"sdg_mappings":[{"sdg_number":0,"sdg_label":"Clean water and sanitation"}],"linked_datasets":[],"clinical_trials":[],"software_tools":[],"database_accessions":[],"source":"live","citation_network_status":"fetched"},"created_at":"2026-06-06T16:33:34.403423Z","pmid":null,"pmcid":null,"fwci":null,"citation_percentile":null,"influential_citations":0,"oa_status":null,"license":null,"views":0,"total_file_size_bytes":0,"version_count":0,"fair_f":null,"fair_a":null,"fair_i":null,"fair_r":null,"fair_zscore":null,"fair_rationale":null,"fair_model":null,"fair_agent_version":null,"fair_fulltext_source":null,"fair_has_llm":null,"fair_computed_at":null,"clinical_trials":[],"software_tools":[],"db_accessions":[],"linked_datasets":[],"topics":[]}