{"doi":"10.1139/v88-461","title":"Phosphoranylation de polyols: Voie d'accès aux phosphates d'intérêt biologique. I. Cas du myo-inositol","abstract":"<jats:p> An original method for the phosphorylation of an unprotected myo-inositol is described, which yields several myo-inositol phosphates at the same time. The reaction proceeds via a partial or complete phosphoranylation of the cyclitol by means of the aminobicyclophosphane 8, followed by oxidation of the resulting bicyclophosphoranes bearing a P—H bond and acid hydrolysis of the neutral phosphates thus formed. In the case of the tris-phosphoranylation we identified, among the HPLC fractions, the myo-inositol-1,2-(cycl)phosphate 22, the myo-inositol-1-phosphate 23, and the myo-inositol-2-phosphate 24. </jats:p>","journal":"Canadian Journal of Chemistry","year":1988,"id":38542,"datarank":1.0270957319102645,"base_score":3.091042453358316,"endowment":3.091042453358316,"self_citation_contribution":0.4636563680037475,"citation_network_contribution":0.5634393639065169,"self_endowment_contribution":0.4636563680037475,"citer_contribution":0.5634393639065169,"corpus_percentile":null,"corpus_rank":null,"citation_count":21,"citer_count":9,"citers_with_citation_signal":7,"citers_with_endowment":7,"datacite_reuse_total":0,"is_dataset":false,"is_dataset_confidence":null,"is_data_producer":false,"deposit_databanks":null,"is_oa":false,"file_count":0,"downloads":0,"has_version_chain":false,"published_date":null,"fair_score":null,"fair_percentile":null,"algorithm_id":"datarank_citation_only_1hop_v6","ranking_scope":"data_only","authors":[{"id":191054,"name":"Douraid Houalla","orcid":null,"position":1,"is_corresponding":false},{"id":191055,"name":"Robert Wolf","orcid":null,"position":2,"is_corresponding":false},{"id":191053,"name":"Brigitte Duthu","orcid":null,"position":0,"is_corresponding":false}],"reference_count":0,"raw_metadata":{"has_enrichment":true,"base_score":3.091042453358316,"endowment":3.091042453358316,"datacite_reuse_total":0,"file_count":0,"downloads":0,"views":0,"has_version_chain":false,"is_dataset":false,"is_oa":false,"pmid":"18998881","pmcid":null,"openalex_id":"https://openalex.org/W2032079956","authors":[],"funders":[],"total_grants":0,"fwci":2.2941,"citation_percentile":0.87829677,"influential_citations":0,"citation_trend":[{"year":2013,"count":2},{"year":2019,"count":1}],"oa_status":"closed","license":"http://www.nrcresearchpress.com/page/about/CorporateTextAndDataMining","oa_locations":[{"url":"https://cdnsciencepub.com/doi/pdf/10.1139/v88-461","host_type":"publisher"},{"url":"https://doi.org/10.1139/v88-461","host_type":"journal"}],"fields_of_study":["Phytase and its Applications","Chemistry","Biology"],"mesh_terms":[],"keywords":["Cyclitol","Chemistry","Inositol","Phosphate","Hydrolysis","Stereochemistry","Inositol phosphate","Tris","INT","Phosphorylation","Sugar phosphates","Biochemistry","Receptor"],"sdg_mappings":[{"sdg_number":0,"sdg_label":"Clean water and sanitation"}],"linked_datasets":[],"clinical_trials":[],"software_tools":[],"database_accessions":[],"source":"live","citation_network_status":"fetched"},"created_at":"2026-06-11T04:11:14.631687Z","pmid":null,"pmcid":null,"fwci":null,"citation_percentile":null,"influential_citations":0,"oa_status":null,"license":null,"views":0,"total_file_size_bytes":0,"version_count":0,"fair_f":null,"fair_a":null,"fair_i":null,"fair_r":null,"fair_zscore":null,"fair_rationale":null,"fair_model":null,"fair_agent_version":null,"fair_fulltext_source":null,"fair_has_llm":null,"fair_computed_at":null,"clinical_trials":[],"software_tools":[],"db_accessions":[],"linked_datasets":[],"topics":[]}