{"doi":"10.1063/1.454293","title":"Statistical thermodynamics of the melting curve at high pressures","abstract":"<jats:p>The thermal potential concept used in earlier publications to calculate zero pressure thermodynamic properties of solids is extended to calculations for elevated pressures. The proposed equations indicate that the theory applied to the melting process generally results in a nonlinear melting curve with the amount of curvature depending on the magnitudes of the potential parameters. Calculations for the T–P melting curve for KCl reproduce the main features of the experimental curve without any assumptions concerning the reordering of the liquid to a more densely packed arrangement. In addition, the theory makes some novel predictions concerning the behavior of some thermodynamic variables at high pressures that can be tested in principle by experiment.</jats:p>","journal":"The Journal of Chemical Physics","year":1988,"id":27902,"datarank":0.11838648549941762,"base_score":0.6931471805599453,"endowment":0.6931471805599453,"self_citation_contribution":0.10397207708399181,"citation_network_contribution":0.014414408415425808,"self_endowment_contribution":0.10397207708399181,"citer_contribution":0.014414408415425808,"corpus_percentile":null,"corpus_rank":null,"citation_count":1,"citer_count":1,"citers_with_citation_signal":1,"citers_with_endowment":1,"datacite_reuse_total":0,"is_dataset":false,"is_dataset_confidence":null,"is_data_producer":false,"deposit_databanks":null,"is_oa":false,"file_count":0,"downloads":0,"has_version_chain":false,"published_date":null,"fair_score":null,"fair_percentile":null,"algorithm_id":"datarank_citation_only_1hop_v6","ranking_scope":"data_only","authors":[{"id":157737,"name":"A. R. Ruffa","orcid":null,"position":0,"is_corresponding":false}],"reference_count":0,"raw_metadata":{"has_enrichment":true,"base_score":0.6931471805599453,"endowment":0.6931471805599453,"datacite_reuse_total":0,"file_count":0,"downloads":0,"views":0,"has_version_chain":false,"is_dataset":false,"is_oa":false,"pmid":"24523987","pmcid":null,"openalex_id":"https://openalex.org/W2019172477","authors":[],"funders":[],"total_grants":0,"fwci":0.3272,"citation_percentile":0.56014937,"influential_citations":0,"citation_trend":[],"oa_status":"bronze","license":null,"oa_locations":[{"url":"https://pubs.aip.org/aip/jcp/article-pdf/88/12/7807/15358646/7807_1_online.pdf","host_type":"journal"},{"url":"https://pubs.aip.org/aip/jcp/article-pdf/88/12/7807/15358646/7807_1_online.pdf","host_type":"BRONZE"},{"url":"https://pubs.aip.org/aip/jcp/article-pdf/88/12/7807/15358646/7807_1_online.pdf","host_type":"publisher"},{"url":"https://pubs.aip.org/aip/jcp/article-pdf/88/12/7807/18970770/7807_1_online.pdf","host_type":"publisher"},{"url":"https://doi.org/10.1063/1.454293","host_type":"journal"}],"fields_of_study":["nanoparticles nucleation surface interactions","Material Dynamics and Properties","Phase Equilibria and Thermodynamics","Chemistry","Physics"],"mesh_terms":[],"keywords":["Thermodynamics","Melting curve analysis","Curvature","Chemistry","Binodal","Materials science","Physics","Mathematics","Phase diagram"],"sdg_mappings":[],"linked_datasets":[],"clinical_trials":[],"software_tools":[],"database_accessions":[],"source":"live","citation_network_status":"fetched"},"created_at":"2026-06-08T19:51:57.747687Z","pmid":null,"pmcid":null,"fwci":null,"citation_percentile":null,"influential_citations":0,"oa_status":null,"license":null,"views":0,"total_file_size_bytes":0,"version_count":0,"fair_f":null,"fair_a":null,"fair_i":null,"fair_r":null,"fair_zscore":null,"fair_rationale":null,"fair_model":null,"fair_agent_version":null,"fair_fulltext_source":null,"fair_has_llm":null,"fair_computed_at":null,"clinical_trials":[],"software_tools":[],"db_accessions":[],"linked_datasets":[],"topics":[]}