{"doi":"10.1055/s-0040-1707156","title":"Rhodium(I) Complexes as Useful Tools for the Activation of Fluoroolefins","abstract":"<jats:p>In this account we describe studies on the reactivity of rhodium(I) complexes of the type [Rh(E)(PEt3)3], where E represents hydrido, fluorido, germyl, boryl or silyl ligands, towards fluorinated olefins. The results are compared with those reported by other research groups on fluoroolefins, as well as with the chemistry of compounds [Rh(E)(PEt3)3] towards fluoroaromatics in terms of selectivity and mechanisms.</jats:p><jats:p>1 \tIntroduction</jats:p><jats:p>2 \tReactivity Towards Fluoroolefins</jats:p><jats:p>2.1 \tReactivity of Hexafluoropropene</jats:p><jats:p>2.2 \tReactivity of (E)-1,2,3,3,3-Pentafluoropropene</jats:p><jats:p>2.3 \tReactivity of 2,3,3,3-Tetrafluoropropene and (E)-1,3,3,3-Tetrafluoropropene</jats:p><jats:p>2.4 \tReactivity of 3,3,3-Trifluoropropene</jats:p><jats:p>2.5 \tReactivity of Pentafluorostyrene</jats:p><jats:p>3 \tConclusion and Perspective</jats:p>","journal":"Synlett","year":2020,"id":614761,"datarank":0.42498200160843247,"base_score":2.833213344056216,"endowment":2.833213344056216,"self_citation_contribution":0.42498200160843247,"citation_network_contribution":0.0,"self_endowment_contribution":0.42498200160843247,"citer_contribution":0.0,"corpus_percentile":null,"corpus_rank":null,"citation_count":16,"citer_count":0,"citers_with_citation_signal":0,"citers_with_endowment":0,"datacite_reuse_total":0,"is_dataset":false,"is_dataset_confidence":null,"is_data_producer":false,"deposit_databanks":null,"is_oa":false,"file_count":0,"downloads":0,"has_version_chain":false,"published_date":null,"fair_score":null,"fair_percentile":null,"algorithm_id":"datarank_citation_only_1hop_v6","ranking_scope":"data_only","authors":[{"id":1584250,"name":"María Talavera","orcid":"0000-0003-2635-4133","position":1,"is_corresponding":false},{"id":225775,"name":"Thomas Braun","orcid":"0000-0002-1416-2065","position":0,"is_corresponding":false}],"reference_count":0,"raw_metadata":{"has_enrichment":true,"resolved":true,"title":"Rhodium(I) Complexes as Useful Tools for the Activation of Fluoroolefins","abstract":"<jats:p>In this account we describe studies on the reactivity of rhodium(I) complexes of the type [Rh(E)(PEt3)3], where E represents hydrido, fluorido, germyl, boryl or silyl ligands, towards fluorinated olefins. The results are compared with those reported by other research groups on fluoroolefins, as well as with the chemistry of compounds [Rh(E)(PEt3)3] towards fluoroaromatics in terms of selectivity and mechanisms.</jats:p><jats:p>1 \tIntroduction</jats:p><jats:p>2 \tReactivity Towards Fluoroolefins</jats:p><jats:p>2.1 \tReactivity of Hexafluoropropene</jats:p><jats:p>2.2 \tReactivity of (E)-1,2,3,3,3-Pentafluoropropene</jats:p><jats:p>2.3 \tReactivity of 2,3,3,3-Tetrafluoropropene and (E)-1,3,3,3-Tetrafluoropropene</jats:p><jats:p>2.4 \tReactivity of 3,3,3-Trifluoropropene</jats:p><jats:p>2.5 \tReactivity of Pentafluorostyrene</jats:p><jats:p>3 \tConclusion and Perspective</jats:p>","is_dataset_classified":null,"base_score":2.833213344056216,"endowment":2.833213344056216,"datacite_reuse_total":0,"file_count":0,"downloads":0,"views":0,"has_version_chain":false,"is_dataset":false,"is_oa":false,"pmid":"21097893","pmcid":null,"openalex_id":"https://openalex.org/W3037142710","authors":[],"funders":[{"funder_name":"Deutsche Forschungsgemeinschaft","grant_id":"387284271 – SFB 1349","title":null},{"funder_name":"Deutsche Forschungsgemeinschaft","grant_id":"unidentified","title":"unidentified"}],"total_grants":2,"fwci":0.781,"citation_percentile":0.64105747,"influential_citations":0,"citation_trend":[{"year":2021,"count":3},{"year":2022,"count":6},{"year":2023,"count":1},{"year":2024,"count":2},{"year":2025,"count":3},{"year":2026,"count":1}],"oa_status":"closed","license":null,"oa_locations":[{"url":"http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-0040-1707156.pdf","host_type":"publisher"},{"url":"https://doi.org/10.1055/s-0040-1707156","host_type":"journal"},{"url":"https://dx.doi.org/10.1055/s-0040-1707156","host_type":""}],"fields_of_study":["Fluorine in Organic Chemistry","Inorganic Fluorides and Related Compounds","01 natural sciences","0104 chemical sciences"],"mesh_terms":[],"keywords":["Reactivity (psychology)","Chemistry","Rhodium","Silylation","Selectivity","Medicinal chemistry","Catalysis","Organic chemistry"],"sdg_mappings":[{"sdg_number":3,"sdg_label":"3. 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