{"doi":"10.1039/p19740001053","title":"Use of carbohydrate derivatives for studies of phosphorus stereochemistry. Part III. Stereochemical course of nucleophilic displacements of 2-substituents in 1,3,2-dioxaphosphorinan-2-ones and related compounds","abstract":null,"journal":"Journal of the Chemical Society, Perkin Transactions 1","year":1974,"id":657510,"datarank":1.43306976514762,"base_score":2.9444389791664403,"endowment":2.9444389791664403,"self_citation_contribution":0.44166584687496613,"citation_network_contribution":0.9914039182726538,"self_endowment_contribution":0.44166584687496613,"citer_contribution":0.9914039182726538,"corpus_percentile":null,"corpus_rank":null,"citation_count":18,"citer_count":15,"citers_with_citation_signal":13,"citers_with_endowment":13,"datacite_reuse_total":0,"is_dataset":false,"is_dataset_confidence":null,"is_data_producer":false,"deposit_databanks":null,"is_oa":false,"file_count":0,"downloads":0,"has_version_chain":false,"published_date":null,"fair_score":null,"fair_percentile":null,"algorithm_id":"datarank_citation_only_1hop_v6","ranking_scope":"data_only","authors":[{"id":1716412,"name":"Thomas D. Inch","orcid":null,"position":1,"is_corresponding":false},{"id":1716413,"name":"Gilbert J. Lewis","orcid":null,"position":2,"is_corresponding":false},{"id":1716411,"name":"John M. Harrison","orcid":null,"position":0,"is_corresponding":false}],"reference_count":0,"raw_metadata":{"has_enrichment":true,"resolved":true,"title":"Use of carbohydrate derivatives for studies of phosphorus stereochemistry. Part III. Stereochemical course of nucleophilic displacements of 2-substituents in 1,3,2-dioxaphosphorinan-2-ones and related compounds","abstract":"The stereochemistry of displacement of 2-substituents from 1,3,2-dioxaphosphorinan-2-ones, 1,3,2-oxathiaphosphorinan-2-ones, and 1,3,2-dioxaphosphorinan-2-thiones has been shown to depend on the nature of both the entering and the leaving group. Inversion of configuration has been observed for reactions involving good leaving groups and weak nucleophiles whereas with less good leaving groups and stronger nucleophiles the displacement reactions proceed with retention of configuration.","is_dataset_classified":null,"base_score":2.9444389791664403,"endowment":2.9444389791664403,"datacite_reuse_total":0,"file_count":0,"downloads":0,"views":0,"has_version_chain":false,"is_dataset":false,"is_oa":false,"pmid":"19162232","pmcid":null,"openalex_id":"https://openalex.org/W2073575063","authors":[],"funders":[],"total_grants":0,"fwci":2.0128,"citation_percentile":0.83630884,"influential_citations":0,"citation_trend":[{"year":2014,"count":1},{"year":2021,"count":1},{"year":2023,"count":1}],"oa_status":"closed","license":null,"oa_locations":[{"url":"http://pubs.rsc.org/en/content/articlepdf/1974/P1/P19740001053","host_type":"publisher"},{"url":"https://doi.org/10.1039/p19740001053","host_type":"journal"}],"fields_of_study":["Organophosphorus compounds synthesis","Phosphorus compounds and reactions","Synthesis and Reactivity of Sulfur-Containing Compounds"],"mesh_terms":[],"keywords":["Nucleophile","Chemistry","Leaving group","Walden inversion","Stereochemistry","Carbohydrate","Group (periodic table)","Inversion (geology)","Displacement (psychology)","Computational chemistry","Organic chemistry","Catalysis"],"sdg_mappings":[{"sdg_number":0,"sdg_label":"Clean water and sanitation"}],"linked_datasets":[],"clinical_trials":[],"software_tools":[],"database_accessions":[],"source":"live","citation_network_status":"fetched"},"created_at":"2026-08-12T01:22:58.170177Z","pmid":null,"pmcid":null,"fwci":null,"citation_percentile":null,"influential_citations":0,"oa_status":null,"license":null,"views":0,"total_file_size_bytes":0,"version_count":0,"fair_f":null,"fair_a":null,"fair_i":null,"fair_r":null,"fair_zscore":null,"fair_rationale":null,"fair_model":null,"fair_agent_version":null,"fair_fulltext_source":null,"fair_has_llm":null,"fair_computed_at":null,"clinical_trials":[],"software_tools":[],"db_accessions":[],"linked_datasets":[],"topics":[]}