{"doi":"10.1039/d5su00574d","title":"Triggering hydrogenolysis of the lignin model compound benzyl phenyl ether using the intrinsic exothermicity of Pd-hydride formation","abstract":"for Pd supported on carbon, silica and alumina, respectively. BPE conversion increased with increasing heat flow, which correlated with a higher Pd particle dispersion and lower heat capacity of the support. X-ray absorption spectroscopy at the Pd-K edge confirms Pd-hydride formation. This work shows that the heat released by Pd-H formation can be used as an initiator for α-O-4 ether cleavage in a solid lignin model compound.","journal":"RSC Sustainability","year":2025,"id":578179,"datarank":0.0,"base_score":0.0,"endowment":0.0,"self_citation_contribution":0.0,"citation_network_contribution":0.0,"self_endowment_contribution":0.0,"citer_contribution":0.0,"corpus_percentile":null,"corpus_rank":null,"citation_count":0,"citer_count":0,"citers_with_citation_signal":0,"citers_with_endowment":0,"datacite_reuse_total":0,"is_dataset":false,"is_dataset_confidence":0.9546,"is_data_producer":false,"deposit_databanks":null,"is_oa":true,"file_count":0,"downloads":0,"has_version_chain":false,"published_date":"2025-01-01","fair_score":null,"fair_percentile":null,"algorithm_id":"datarank_citation_only_1hop_v6","ranking_scope":"data_only","authors":[{"id":1487834,"name":"Marta C. Hatzell","orcid":"0000-0002-5144-4969","position":1,"is_corresponding":false},{"id":724443,"name":"Carsten Sievers","orcid":"0000-0002-5713-1875","position":2,"is_corresponding":false},{"id":1487833,"name":"Erin V. Phillips","orcid":"0000-0003-1352-2265","position":0,"is_corresponding":true}],"reference_count":72,"raw_metadata":null,"created_at":"2026-07-19T02:58:20.638044Z","pmid":"41089091","pmcid":null,"fwci":null,"citation_percentile":null,"influential_citations":0,"oa_status":null,"license":null,"views":0,"total_file_size_bytes":0,"version_count":0,"fair_f":null,"fair_a":null,"fair_i":null,"fair_r":null,"fair_zscore":null,"fair_rationale":null,"fair_model":null,"fair_agent_version":null,"fair_fulltext_source":null,"fair_has_llm":null,"fair_computed_at":null,"clinical_trials":[],"software_tools":[],"db_accessions":[],"linked_datasets":[],"topics":[]}