{"doi":"10.1039/d4sm00246f","title":"Cosolvent incorporation modulates the thermal and structural response of PNIPAM/silyl methacrylate copolymers","abstract":"purely aqueous systems, these solvent mixtures can introduce additional phase transitions and can alter the two-phase region boundaries based on temperature and solvent composition. Interestingly, TMA incorporation strongly alters phase boundaries in the water-rich regime for DMF-containing systems but not for ethanol-containing systems. Cosolvent species and content also alter the aggregation and assembly of NIPAM/TMA copolymers, but these effects depend on polymer architecture. For example, localizing the TMA towards one chain end in 'blocky' domains leads to formation of uniform micelles with narrow dispersities above the cloud point for certain solvent compositions. In contrast, polydisperse aggregates form in random copolymer and PNIPAM homopolymer solutions - the size of which depends on solvent composition. The resulting optical responses and thermoreversibility also depend strongly on cosolvent content and copolymer architecture. Cosolvent incorporation thus increases the versatility of inorganic-functionalized responsive polymers for diverse applications by providing a simple way to tune the structure size and optical response.","journal":"Soft Matter","year":2024,"id":470707,"datarank":0.0,"base_score":0.0,"endowment":0.0,"self_citation_contribution":0.0,"citation_network_contribution":0.0,"self_endowment_contribution":0.0,"citer_contribution":0.0,"corpus_percentile":null,"corpus_rank":null,"citation_count":2,"citer_count":0,"citers_with_citation_signal":0,"citers_with_endowment":0,"datacite_reuse_total":0,"is_dataset":false,"is_dataset_confidence":0.9539,"is_data_producer":false,"deposit_databanks":null,"is_oa":true,"file_count":0,"downloads":0,"has_version_chain":false,"published_date":"2024-01-01","fair_score":null,"fair_percentile":null,"algorithm_id":"datarank_citation_only_1hop_v6","ranking_scope":"data_only","authors":[{"id":1305076,"name":"Fabián A. Rodríguez","orcid":"0009-0004-0596-0702","position":1,"is_corresponding":false},{"id":812288,"name":"Michelle A. Calabrese","orcid":"0000-0003-4577-6999","position":2,"is_corresponding":false},{"id":956844,"name":"Jason D. Linn","orcid":"0000-0002-2722-5942","position":0,"is_corresponding":true}],"reference_count":76,"raw_metadata":null,"created_at":"2026-07-19T02:05:40.740958Z","pmid":"38536224","pmcid":null,"fwci":null,"citation_percentile":null,"influential_citations":0,"oa_status":null,"license":null,"views":0,"total_file_size_bytes":0,"version_count":0,"fair_f":null,"fair_a":null,"fair_i":null,"fair_r":null,"fair_zscore":null,"fair_rationale":null,"fair_model":null,"fair_agent_version":null,"fair_fulltext_source":null,"fair_has_llm":null,"fair_computed_at":null,"clinical_trials":[],"software_tools":[],"db_accessions":[],"linked_datasets":[],"topics":[]}