{"doi":"10.1039/d4sc06023g","title":"Tunable synthesis of heteroleptic zirconium-based porous coordination cages","abstract":", geometry containing 3 : 3 ratios of combinations of two types of functional moieties from 11 different ligand options. Additionally, using more sterically hindered ligands, such as 5-benzyloxybenzene dicarboxylate, we show that ligand size governs the resulting cage geometry. This method allows for multiple functional groups to be incorporated in molecular cages and the ratio of moieties incorporated can be easily controlled. With this strategy in hand, we show that ligands for which zirconium cage syntheses have been elusive, such as 2,5-dihydroxybenzene dicarboxylate, have now been successfully incorporated into porous structures.","journal":"Chemical Science","year":2024,"id":458808,"datarank":0.0,"base_score":0.0,"endowment":0.0,"self_citation_contribution":0.0,"citation_network_contribution":0.0,"self_endowment_contribution":0.0,"citer_contribution":0.0,"corpus_percentile":null,"corpus_rank":null,"citation_count":5,"citer_count":0,"citers_with_citation_signal":0,"citers_with_endowment":0,"datacite_reuse_total":0,"is_dataset":false,"is_dataset_confidence":0.9478,"is_data_producer":false,"deposit_databanks":null,"is_oa":true,"file_count":0,"downloads":0,"has_version_chain":false,"published_date":"2024-01-01","fair_score":null,"fair_percentile":null,"algorithm_id":"datarank_citation_only_1hop_v6","ranking_scope":"data_only","authors":[{"id":1080276,"name":"Christine M. Montone","orcid":null,"position":1,"is_corresponding":false},{"id":919119,"name":"Michael R. Dworzak","orcid":null,"position":2,"is_corresponding":false},{"id":562200,"name":"Glenn P. A. Yap","orcid":"0000-0003-0385-387X","position":3,"is_corresponding":false},{"id":918638,"name":"Eric D. Bloch","orcid":"0000-0003-4507-6247","position":4,"is_corresponding":false},{"id":1285101,"name":"Merissa N. Morey","orcid":"0000-0003-2723-7254","position":0,"is_corresponding":true}],"reference_count":60,"raw_metadata":null,"created_at":"2026-07-19T02:03:50.608887Z","pmid":"39640028","pmcid":null,"fwci":null,"citation_percentile":null,"influential_citations":0,"oa_status":null,"license":null,"views":0,"total_file_size_bytes":0,"version_count":0,"fair_f":null,"fair_a":null,"fair_i":null,"fair_r":null,"fair_zscore":null,"fair_rationale":null,"fair_model":null,"fair_agent_version":null,"fair_fulltext_source":null,"fair_has_llm":null,"fair_computed_at":null,"clinical_trials":[],"software_tools":[],"db_accessions":[],"linked_datasets":[],"topics":[]}