{"doi":"10.1039/d3cc02015k","title":"Rapid post-synthetic modification of porous coordination cages with copper-catalyzed click chemistry","abstract":"Novel cobalt calixarene-capped and zirconium-based porous coordination cages were prepared with alkyne and azide functionality to leverage post-synthetic modification by click chemistry. While the calixarene-capped cages showed impressive stability when exposed to the most straightforward copper(I)-catalyzed alkyne-azide cycloaddition (CuAAC) reaction conditions with copper(II) sulfate and sodium ascorbate as the reducing agent, milder reaction conditions were necessary to perform analogous CuAAC reactions on zirconium-based cages. Reaction kinetics were monitored by IR spectroscopy, confirming rapid reaction times (<3 hours).","journal":"Chemical Communications","year":2023,"id":342728,"datarank":0.0,"base_score":0.0,"endowment":0.0,"self_citation_contribution":0.0,"citation_network_contribution":0.0,"self_endowment_contribution":0.0,"citer_contribution":0.0,"corpus_percentile":null,"corpus_rank":null,"citation_count":14,"citer_count":0,"citers_with_citation_signal":0,"citers_with_endowment":0,"datacite_reuse_total":0,"is_dataset":false,"is_dataset_confidence":0.9469,"is_data_producer":false,"deposit_databanks":null,"is_oa":true,"file_count":0,"downloads":0,"has_version_chain":false,"published_date":"2023-01-01","fair_score":null,"fair_percentile":null,"algorithm_id":"datarank_citation_only_1hop_v6","ranking_scope":"data_only","authors":[{"id":1080276,"name":"Christine M. Montone","orcid":null,"position":1,"is_corresponding":false},{"id":1079709,"name":"Nicole I. Halaszynski","orcid":"0009-0002-5708-5722","position":2,"is_corresponding":false},{"id":562200,"name":"Glenn P. A. Yap","orcid":"0000-0003-0385-387X","position":3,"is_corresponding":false},{"id":516480,"name":"Christopher J. Kloxin","orcid":"0000-0002-1679-0022","position":4,"is_corresponding":false},{"id":918638,"name":"Eric D. Bloch","orcid":"0000-0003-4507-6247","position":5,"is_corresponding":false},{"id":919119,"name":"Michael R. Dworzak","orcid":null,"position":0,"is_corresponding":true}],"reference_count":36,"raw_metadata":null,"created_at":"2026-07-19T01:11:17.288563Z","pmid":"37387311","pmcid":null,"fwci":null,"citation_percentile":null,"influential_citations":0,"oa_status":null,"license":null,"views":0,"total_file_size_bytes":0,"version_count":0,"fair_f":null,"fair_a":null,"fair_i":null,"fair_r":null,"fair_zscore":null,"fair_rationale":null,"fair_model":null,"fair_agent_version":null,"fair_fulltext_source":null,"fair_has_llm":null,"fair_computed_at":null,"clinical_trials":[],"software_tools":[],"db_accessions":[],"linked_datasets":[],"topics":[]}