{"doi":"10.1039/d2sc01042a","title":"C2-ketonylation of carbohydrates <i>via</i> excited-state palladium-catalyzed 1,2-spin-center shift","abstract":"an excited-state palladium-catalyzed 1,2-spin-center shift (SCS) process. This step-economic reaction features broad substrate scope, has a high functional group tolerance, and can be used in late-stage functionalization of natural product- and drug-glycoconjugates. Preliminary experimental and computational mechanistic studies suggested a non-chain radical mechanism involving photoexcited palladium species, a 1,2-SCS process, and a radical Mizoroki-Heck reaction.","journal":"Chemical Science","year":2022,"id":240233,"datarank":0.0,"base_score":0.0,"endowment":0.0,"self_citation_contribution":0.0,"citation_network_contribution":0.0,"self_endowment_contribution":0.0,"citer_contribution":0.0,"corpus_percentile":null,"corpus_rank":null,"citation_count":46,"citer_count":0,"citers_with_citation_signal":0,"citers_with_endowment":0,"datacite_reuse_total":0,"is_dataset":false,"is_dataset_confidence":0.9496,"is_data_producer":false,"deposit_databanks":null,"is_oa":true,"file_count":0,"downloads":0,"has_version_chain":false,"published_date":"2022-01-01","fair_score":null,"fair_percentile":null,"algorithm_id":"datarank_citation_only_1hop_v6","ranking_scope":"data_only","authors":[{"id":867418,"name":"Upasana Mukherjee","orcid":"0000-0003-0504-7695","position":1,"is_corresponding":false},{"id":285940,"name":"Ling Zhou","orcid":"0000-0002-6805-2961","position":2,"is_corresponding":false},{"id":867419,"name":"Yue Wu","orcid":"0000-0003-1579-247X","position":3,"is_corresponding":false},{"id":636064,"name":"Wang Yao","orcid":"0000-0001-8708-2851","position":4,"is_corresponding":false},{"id":867420,"name":"Jaclyn N. Mauro","orcid":"0000-0002-2018-8325","position":5,"is_corresponding":false},{"id":285942,"name":"Peng Liu","orcid":"0000-0002-8188-632X","position":6,"is_corresponding":false},{"id":636065,"name":"Ming‐Yu Ngai","orcid":"0000-0002-3055-6662","position":7,"is_corresponding":false},{"id":867417,"name":"Gaoyuan Zhao","orcid":"0000-0003-4838-865X","position":0,"is_corresponding":true}],"reference_count":83,"raw_metadata":null,"created_at":"2026-07-19T00:22:46.554789Z","pmid":"35733909","pmcid":null,"fwci":null,"citation_percentile":null,"influential_citations":0,"oa_status":null,"license":null,"views":0,"total_file_size_bytes":0,"version_count":0,"fair_f":null,"fair_a":null,"fair_i":null,"fair_r":null,"fair_zscore":null,"fair_rationale":null,"fair_model":null,"fair_agent_version":null,"fair_fulltext_source":null,"fair_has_llm":null,"fair_computed_at":null,"clinical_trials":[],"software_tools":[],"db_accessions":[],"linked_datasets":[],"topics":[]}