{"doi":"10.1039/d0dt01801e","title":"Heterobimetallic complexes of IrM (M = Fe <sup>II</sup> , Co <sup>II</sup> , and Ni <sup>II</sup> ) core and bridging 2-(diphenylphosphino)pyridine: electronic structure and electrochemical behavior","abstract":"orbital on iridium and an empty orbital on the first-row metal atom, which is supported by UV-vis studies. Magnetic moment measurements show that the first-row metals are in their high-spin electronic configurations. Cyclic voltammetry data show that all the complexes undergo irreversible decomposition upon either reduction or oxidation. Reduction of 4 proceeds through an ECE mechanism. While these complexes are not stable to electrocatalysis conditions, the data presented here refine our understanding of the bonding synergies of the first-row and third-row metals.","journal":"Dalton Transactions","year":2020,"id":114559,"datarank":0.0,"base_score":0.0,"endowment":0.0,"self_citation_contribution":0.0,"citation_network_contribution":0.0,"self_endowment_contribution":0.0,"citer_contribution":0.0,"corpus_percentile":null,"corpus_rank":null,"citation_count":5,"citer_count":0,"citers_with_citation_signal":0,"citers_with_endowment":0,"datacite_reuse_total":0,"is_dataset":false,"is_dataset_confidence":0.951,"is_data_producer":false,"deposit_databanks":null,"is_oa":true,"file_count":0,"downloads":0,"has_version_chain":false,"published_date":"2020-01-01","fair_score":null,"fair_percentile":null,"algorithm_id":"datarank_citation_only_1hop_v6","ranking_scope":"data_only","authors":[{"id":538045,"name":"Ashley N. Hellman","orcid":"0000-0002-1600-4888","position":1,"is_corresponding":false},{"id":538046,"name":"Zhenzhuo Lan","orcid":"0000-0003-2531-6338","position":2,"is_corresponding":false},{"id":365972,"name":"Shaama Mallikarjun Sharada","orcid":"0000-0001-7332-5373","position":3,"is_corresponding":false},{"id":365973,"name":"Travis J. Williams","orcid":"0000-0001-6299-3747","position":4,"is_corresponding":false},{"id":365969,"name":"Valeriy Cherepakhin","orcid":"0000-0003-1966-9794","position":0,"is_corresponding":true}],"reference_count":34,"raw_metadata":null,"created_at":"2026-07-18T23:13:29.674622Z","pmid":"32748911","pmcid":null,"fwci":null,"citation_percentile":null,"influential_citations":0,"oa_status":null,"license":null,"views":0,"total_file_size_bytes":0,"version_count":0,"fair_f":null,"fair_a":null,"fair_i":null,"fair_r":null,"fair_zscore":null,"fair_rationale":null,"fair_model":null,"fair_agent_version":null,"fair_fulltext_source":null,"fair_has_llm":null,"fair_computed_at":null,"clinical_trials":[],"software_tools":[],"db_accessions":[],"linked_datasets":[],"topics":[]}