{"doi":"10.1021/jacs.4c12787","title":"Intermolecular N–N Coupling of a Dinitrosyl Iron Complex Induced by Hydrogen Bond Donors in the Secondary Coordination Sphere","abstract":"High Resolution Image Download MS PowerPoint Slide The intermolecular N–N coupling of NO in a dinitrosyl iron complex (DNIC) induced by hydrogen bond donors in the secondary coordination sphere to form N 2 O is reported. A family of complexes containing pendant anilines in the secondary coordination sphere were synthesized and characterized. Reduction of the {Fe(NO) 2 } 9 complex [Fe( PhNH PDI)(NO) 2 ][BPh 4 ] ( 3 ) to the {Fe(NO) 2 } 10 Fe( PhNH PDI)(NO) 2 ( 4 ) results in intermolecular N–N coupling to form N 2 O. Similar reactions of the control {Fe(NO) 2 } 9 complex [Fe( PhNMe PDI)(NO) 2 ][BPh 4 ] ( 7 ), which does not have H-bonding groups in the secondary coordination sphere, do not result in N 2 O formation. The hydrogen bonding capabilities of the complexes were explored spectroscopically and computationally.","journal":"Journal of the American Chemical Society","year":2025,"id":519086,"datarank":0.0,"base_score":0.0,"endowment":0.0,"self_citation_contribution":0.0,"citation_network_contribution":0.0,"self_endowment_contribution":0.0,"citer_contribution":0.0,"corpus_percentile":null,"corpus_rank":null,"citation_count":6,"citer_count":0,"citers_with_citation_signal":0,"citers_with_endowment":0,"datacite_reuse_total":0,"is_dataset":false,"is_dataset_confidence":0.9594,"is_data_producer":false,"deposit_databanks":null,"is_oa":true,"file_count":0,"downloads":0,"has_version_chain":false,"published_date":"2025-01-01","fair_score":null,"fair_percentile":null,"algorithm_id":"datarank_citation_only_1hop_v6","ranking_scope":"data_only","authors":[{"id":1387433,"name":"Gabriel S. Black","orcid":null,"position":1,"is_corresponding":false},{"id":614515,"name":"Tim Kowalczyk","orcid":"0000-0003-1806-059X","position":2,"is_corresponding":false},{"id":1387434,"name":"Takele Seda","orcid":null,"position":3,"is_corresponding":false},{"id":415344,"name":"John D. Gilbertson","orcid":"0000-0003-2450-0846","position":4,"is_corresponding":false},{"id":1387432,"name":"Kayla M. Fugami","orcid":null,"position":0,"is_corresponding":true}],"reference_count":43,"raw_metadata":null,"created_at":"2026-07-19T02:49:14.184995Z","pmid":"39969499","pmcid":null,"fwci":null,"citation_percentile":null,"influential_citations":0,"oa_status":null,"license":null,"views":0,"total_file_size_bytes":0,"version_count":0,"fair_f":null,"fair_a":null,"fair_i":null,"fair_r":null,"fair_zscore":null,"fair_rationale":null,"fair_model":null,"fair_agent_version":null,"fair_fulltext_source":null,"fair_has_llm":null,"fair_computed_at":null,"clinical_trials":[],"software_tools":[],"db_accessions":[],"linked_datasets":[],"topics":[]}