{"doi":"10.1021/jacs.3c08151","title":"Synthesis of Allenes by Hydroalkylation of 1,3-Enynes with Ketones Enabled by Cooperative Catalysis","abstract":"A method for the synthesis of allenes by the addition of ketones to 1,3-enynes by cooperative Pd(0)Senphos/B(C 6 F 5 ) 3 /NR 3 catalysis is described. A wide range of aryl- and aliphatic ketones undergo addition to various 1,3-enynes in high yields at room temperature. Mechanistic investigations revealed a rate-determining outer-sphere proton transfer mechanism, which was corroborated by DFT calculations.","journal":"Journal of the American Chemical Society","year":2023,"id":343310,"datarank":0.0,"base_score":0.0,"endowment":0.0,"self_citation_contribution":0.0,"citation_network_contribution":0.0,"self_endowment_contribution":0.0,"citer_contribution":0.0,"corpus_percentile":null,"corpus_rank":null,"citation_count":14,"citer_count":0,"citers_with_citation_signal":0,"citers_with_endowment":0,"datacite_reuse_total":0,"is_dataset":false,"is_dataset_confidence":0.95,"is_data_producer":false,"deposit_databanks":null,"is_oa":true,"file_count":0,"downloads":0,"has_version_chain":false,"published_date":"2023-01-01","fair_score":null,"fair_percentile":null,"algorithm_id":"datarank_citation_only_1hop_v6","ranking_scope":"data_only","authors":[{"id":1081348,"name":"Yuping Dai","orcid":null,"position":1,"is_corresponding":false},{"id":694783,"name":"Ziyong Wang","orcid":"0000-0002-6585-8951","position":2,"is_corresponding":false},{"id":540813,"name":"Bo Li","orcid":"0000-0001-5763-7262","position":3,"is_corresponding":false},{"id":694785,"name":"Walid Lamine","orcid":"0000-0003-1120-3287","position":4,"is_corresponding":false},{"id":694789,"name":"Karinne Miqueu","orcid":"0000-0002-5960-1877","position":5,"is_corresponding":false},{"id":694790,"name":"Shih‐Yuan Liu","orcid":"0000-0003-3148-9147","position":6,"is_corresponding":false},{"id":1081347,"name":"Maxwell Eaton","orcid":null,"position":0,"is_corresponding":true}],"reference_count":76,"raw_metadata":null,"created_at":"2026-07-19T01:11:21.758449Z","pmid":"37738372","pmcid":null,"fwci":null,"citation_percentile":null,"influential_citations":0,"oa_status":null,"license":null,"views":0,"total_file_size_bytes":0,"version_count":0,"fair_f":null,"fair_a":null,"fair_i":null,"fair_r":null,"fair_zscore":null,"fair_rationale":null,"fair_model":null,"fair_agent_version":null,"fair_fulltext_source":null,"fair_has_llm":null,"fair_computed_at":null,"clinical_trials":[],"software_tools":[],"db_accessions":[],"linked_datasets":[],"topics":[]}