{"doi":"10.1021/jacs.2c09756","title":"Broadly Tunable Atmospheric Water Harvesting in Multivariate Metal–Organic Frameworks","abstract":"Development of multivariate metal–organic frameworks (MOFs) as derivatives of the state-of-art water-harvesting material MOF-303 {[Al(OH)(PZDC)], where PZDC2– is 1H-pyrazole-3,5-dicarboxylate} was shown to be a powerful tool to generate efficient water sorbents tailored to a given environmental condition. Herein, a new multivariate MOF-303-based water-harvesting framework series from readily available reactants is developed. The resulting MOFs exhibit a larger degree of tunability in the operational relative humidity range (16%), regeneration temperature (14 °C), and desorption enthalpy (5 kJ mol–1) than reported previously. Additionally, a high-yielding (≥90%) and scalable (∼3.5 kg) synthesis is demonstrated in water and with excellent space-time yields, without compromising framework crystallinity, porosity, and water-harvesting performance.","journal":"Journal of the American Chemical Society","year":2022,"id":232919,"datarank":0.0,"base_score":0.0,"endowment":0.0,"self_citation_contribution":0.0,"citation_network_contribution":0.0,"self_endowment_contribution":0.0,"citer_contribution":0.0,"corpus_percentile":null,"corpus_rank":null,"citation_count":156,"citer_count":0,"citers_with_citation_signal":0,"citers_with_endowment":0,"datacite_reuse_total":0,"is_dataset":false,"is_dataset_confidence":0.9442,"is_data_producer":false,"deposit_databanks":null,"is_oa":false,"file_count":0,"downloads":0,"has_version_chain":false,"published_date":"2022-01-01","fair_score":null,"fair_percentile":null,"algorithm_id":"datarank_citation_only_1hop_v6","ranking_scope":"data_only","authors":[{"id":231853,"name":"Nikita Hanikel","orcid":"0000-0002-3292-5070","position":1,"is_corresponding":false},{"id":260356,"name":"Hao Lyu","orcid":"0000-0001-7393-2456","position":2,"is_corresponding":false},{"id":58703,"name":"Omar M. Yaghi","orcid":"0000-0002-5611-3325","position":3,"is_corresponding":false},{"id":840055,"name":"Zhiling Zheng","orcid":"0000-0001-6090-2258","position":0,"is_corresponding":true}],"reference_count":24,"raw_metadata":null,"created_at":"2026-07-19T00:21:18.683916Z","pmid":"36446081","pmcid":null,"fwci":null,"citation_percentile":null,"influential_citations":0,"oa_status":null,"license":null,"views":0,"total_file_size_bytes":0,"version_count":0,"fair_f":null,"fair_a":null,"fair_i":null,"fair_r":null,"fair_zscore":null,"fair_rationale":null,"fair_model":null,"fair_agent_version":null,"fair_fulltext_source":null,"fair_has_llm":null,"fair_computed_at":null,"clinical_trials":[],"software_tools":[],"db_accessions":[],"linked_datasets":[],"topics":[]}