{"doi":"10.1021/ja062166r","title":"Aryl-Halide versus Aryl−Aryl Reductive Elimination in Pt(IV)−Phosphine Complexes","abstract":null,"journal":"Journal of the American Chemical Society","year":2006,"id":598751,"datarank":0.6090664515819629,"base_score":4.060443010546419,"endowment":4.060443010546419,"self_citation_contribution":0.6090664515819629,"citation_network_contribution":0.0,"self_endowment_contribution":0.6090664515819629,"citer_contribution":0.0,"corpus_percentile":null,"corpus_rank":null,"citation_count":57,"citer_count":0,"citers_with_citation_signal":0,"citers_with_endowment":0,"datacite_reuse_total":0,"is_dataset":false,"is_dataset_confidence":null,"is_data_producer":false,"deposit_databanks":null,"is_oa":false,"file_count":0,"downloads":0,"has_version_chain":false,"published_date":null,"fair_score":null,"fair_percentile":null,"algorithm_id":"datarank_citation_only_1hop_v6","ranking_scope":"data_only","authors":[{"id":1534484,"name":"Israel Goldberg","orcid":null,"position":1,"is_corresponding":false},{"id":1534486,"name":"Arkadi Vigalok","orcid":null,"position":2,"is_corresponding":false},{"id":1534482,"name":"Anette Yahav-Levi","orcid":null,"position":0,"is_corresponding":false}],"reference_count":0,"raw_metadata":{"has_enrichment":true,"resolved":true,"title":"Aryl-Halide versus Aryl−Aryl Reductive Elimination in Pt(IV)−Phosphine Complexes","abstract":"Upon the addition of Br2 to complexes (P-P)Pt(Ar)2, two different products were observed, depending on the bite angle of the bidentate phosphine ligand: a Pt(II) aryl bromide complex, the product of C-Br reductive elimination, and Pt(IV) oxidative addition complex. At high temperatures, the latter exclusively gave the product of the C-C reductive elimination.","is_dataset_classified":null,"base_score":4.060443010546419,"endowment":4.060443010546419,"datacite_reuse_total":0,"file_count":0,"downloads":0,"views":0,"has_version_chain":false,"is_dataset":false,"is_oa":false,"pmid":"16819847","pmcid":null,"openalex_id":"https://openalex.org/W1984919548","authors":[],"funders":[],"total_grants":0,"fwci":3.4833,"citation_percentile":0.92543514,"influential_citations":0,"citation_trend":[{"year":2012,"count":5},{"year":2013,"count":5},{"year":2014,"count":3},{"year":2015,"count":3},{"year":2016,"count":2},{"year":2018,"count":2},{"year":2019,"count":2},{"year":2020,"count":1},{"year":2021,"count":1},{"year":2024,"count":2}],"oa_status":"closed","license":null,"oa_locations":[{"url":"https://pubs.acs.org/doi/pdf/10.1021/ja062166r","host_type":"publisher"},{"url":"https://doi.org/10.1021/ja062166r","host_type":"journal"},{"url":"https://pubmed.ncbi.nlm.nih.gov/16819847","host_type":"repository"}],"fields_of_study":["Asymmetric Hydrogenation and Catalysis","Catalytic Cross-Coupling Reactions","Asymmetric Synthesis and Catalysis","Crystallography, X-Ray","Hydrocarbons, Halogenated","Models, Molecular","Molecular Structure","Organoplatinum Compounds","Oxidation-Reduction","Phosphines","Stereoisomerism","Time Factors"],"mesh_terms":["Hydrocarbons, Halogenated","Models, Molecular","Organoplatinum Compounds","Oxidation-Reduction","Phosphines","Stereoisomerism","Time Factors","Molecular Structure","Crystallography, X-Ray"],"keywords":["Chemistry","Reductive elimination","Oxidative addition","Aryl","Phosphine","Bromide","Aryl halide","Halide","Medicinal chemistry","Ligand (biochemistry)","Denticity","Stereochemistry","Organic chemistry","Alkyl","Catalysis","Metal"],"sdg_mappings":[{"sdg_number":0,"sdg_label":"Clean water and sanitation"}],"linked_datasets":[],"clinical_trials":[],"software_tools":[],"database_accessions":[],"source":"live","citation_network_status":"fetched"},"created_at":"2026-07-28T16:11:30.768174Z","pmid":null,"pmcid":null,"fwci":null,"citation_percentile":null,"influential_citations":0,"oa_status":null,"license":null,"views":0,"total_file_size_bytes":0,"version_count":0,"fair_f":null,"fair_a":null,"fair_i":null,"fair_r":null,"fair_zscore":null,"fair_rationale":null,"fair_model":null,"fair_agent_version":null,"fair_fulltext_source":null,"fair_has_llm":null,"fair_computed_at":null,"clinical_trials":[],"software_tools":[],"db_accessions":[],"linked_datasets":[],"topics":[]}