{"doi":"10.1021/acs.jpclett.2c00344","title":"Hydroxy Mercapto Methylene: The Missing H<sub>2</sub>CSO Isomer","abstract":null,"journal":"The Journal of Physical Chemistry Letters","year":2022,"id":676768,"datarank":0.16479184330021646,"base_score":1.0986122886681096,"endowment":1.0986122886681096,"self_citation_contribution":0.16479184330021646,"citation_network_contribution":0.0,"self_endowment_contribution":0.16479184330021646,"citer_contribution":0.0,"corpus_percentile":null,"corpus_rank":null,"citation_count":2,"citer_count":0,"citers_with_citation_signal":0,"citers_with_endowment":0,"datacite_reuse_total":0,"is_dataset":false,"is_dataset_confidence":null,"is_data_producer":false,"deposit_databanks":null,"is_oa":false,"file_count":0,"downloads":0,"has_version_chain":false,"published_date":null,"fair_score":null,"fair_percentile":null,"algorithm_id":"datarank_citation_only_1hop_v6","ranking_scope":"data_only","authors":[{"id":506480,"name":"Peter R. Schreiner","orcid":"0000-0002-3608-5515","position":1,"is_corresponding":false},{"id":1768265,"name":"Markus Schauermann","orcid":"0000-0001-8486-2617","position":0,"is_corresponding":false}],"reference_count":0,"raw_metadata":{"has_enrichment":true,"resolved":true,"title":"Hydroxy Mercapto Methylene: The Missing H<sub>2</sub>CSO Isomer","abstract":"We report the isolation of hydroxy mercapto methylene (HO–C̈–SH) under cryogenic conditions via pyrolysis of 2-ethoxy-2-thioxo-acetic acid. The two most stable carbene rotamers form via extrusion of ethylene and CO 2 from this precursor. This donor-stabilized carbene represents a hitherto uncharacterized CH 2 SO species and the first spectroscopically characterized free mercapto carbene. CCSD(T)/cc-pVTZ computations support our findings.","is_dataset_classified":null,"base_score":1.0986122886681096,"endowment":1.0986122886681096,"datacite_reuse_total":0,"file_count":0,"downloads":0,"views":0,"has_version_chain":false,"is_dataset":false,"is_oa":false,"pmid":"35357840","pmcid":null,"openalex_id":"https://openalex.org/W4223452561","authors":[],"funders":[{"funder_name":"Justus Liebig Universit?t Gie?en","grant_id":"","title":null}],"total_grants":1,"fwci":0.1934,"citation_percentile":0.38292702,"influential_citations":0,"citation_trend":[{"year":2022,"count":1},{"year":2024,"count":1}],"oa_status":"closed","license":"https://doi.org/10.15223/policy-029","oa_locations":[{"url":"https://pubs.acs.org/doi/pdf/10.1021/acs.jpclett.2c00344","host_type":"publisher"},{"url":"https://doi.org/10.1021/acs.jpclett.2c00344","host_type":"journal"},{"url":"https://pubmed.ncbi.nlm.nih.gov/35357840","host_type":"repository"}],"fields_of_study":["Molecular Spectroscopy and Structure","Atmospheric Ozone and Climate","Advanced Chemical Physics Studies","Isomerism","Methane"],"mesh_terms":["Isomerism","Methane"],"keywords":["Methylene","Chemistry","Environmental chemistry","Environmental science","Medicinal chemistry"],"sdg_mappings":[],"linked_datasets":[],"clinical_trials":[],"software_tools":[],"database_accessions":[],"source":"live","citation_network_status":"fetched"},"created_at":"2026-08-17T03:03:56.420869Z","pmid":null,"pmcid":null,"fwci":null,"citation_percentile":null,"influential_citations":0,"oa_status":null,"license":null,"views":0,"total_file_size_bytes":0,"version_count":0,"fair_f":null,"fair_a":null,"fair_i":null,"fair_r":null,"fair_zscore":null,"fair_rationale":null,"fair_model":null,"fair_agent_version":null,"fair_fulltext_source":null,"fair_has_llm":null,"fair_computed_at":null,"clinical_trials":[],"software_tools":[],"db_accessions":[],"linked_datasets":[],"topics":[]}