{"doi":"10.1021/acs.jpcc.9b10775","title":"Studying Chemisorption at Metal–Polymer Interfaces by Complementary Use of Attenuated Total Reflection–Fourier Transform Infrared Spectroscopy (ATR-FTIR) in the Kretschmann Geometry and Visible–Infrared Sum-Frequency Generation Spectroscopy (SFG)","abstract":null,"journal":"The Journal of Physical Chemistry C","year":2020,"id":600076,"datarank":0.5416376868966337,"base_score":3.6109179126442243,"endowment":3.6109179126442243,"self_citation_contribution":0.5416376868966337,"citation_network_contribution":0.0,"self_endowment_contribution":0.5416376868966337,"citer_contribution":0.0,"corpus_percentile":null,"corpus_rank":null,"citation_count":36,"citer_count":0,"citers_with_citation_signal":0,"citers_with_endowment":0,"datacite_reuse_total":0,"is_dataset":false,"is_dataset_confidence":null,"is_data_producer":false,"deposit_databanks":null,"is_oa":false,"file_count":0,"downloads":0,"has_version_chain":false,"published_date":null,"fair_score":null,"fair_percentile":null,"algorithm_id":"datarank_citation_only_1hop_v6","ranking_scope":"data_only","authors":[{"id":1538222,"name":"Deborah Ganzinga-Jurg","orcid":null,"position":1,"is_corresponding":false},{"id":1538223,"name":"Jan Versluis","orcid":null,"position":2,"is_corresponding":false},{"id":1538224,"name":"Berend Boelen","orcid":null,"position":3,"is_corresponding":false},{"id":1538225,"name":"Huib J. Bakker","orcid":"0000-0003-1564-5314","position":4,"is_corresponding":false},{"id":1538226,"name":"Herman Terryn","orcid":"0000-0003-2639-5496","position":5,"is_corresponding":false},{"id":1538227,"name":"Johannes M. C. Mol","orcid":"0000-0003-1810-5145","position":6,"is_corresponding":false},{"id":1538221,"name":"Laura-Lynn I. Fockaert","orcid":null,"position":0,"is_corresponding":false}],"reference_count":0,"raw_metadata":{"has_enrichment":true,"resolved":true,"title":"Studying Chemisorption at Metal–Polymer Interfaces by Complementary Use of Attenuated Total Reflection–Fourier Transform Infrared Spectroscopy (ATR-FTIR) in the Kretschmann Geometry and Visible–Infrared Sum-Frequency Generation Spectroscopy (SFG)","abstract":"<p>The molecular configuration and chemistry at the zinc/zinc oxide-polyester interface were studied by using two complementary spectroscopic techniques: attenuated total reflection-Fourier transform infrared spectroscopy (ATR-FTIR) and sum-frequency generation (SFG) spectroscopy. It was shown that ATR-FTIR should be considered as a (3D) interphase-sensitive technique with probing depths of 250-400 nm in the headgroup region (2000-1200 cm<sup>-1</sup>). On the other hand, SFG is known to be a (2D) interface-sensitive technique. The ATR-FTIR measurements showed that carboxylate groups are formed within the near-interface region of the polyester phase. SFG measurements showed that the carboxylic acid groups are stable at the polymer-zinc/zinc oxide interface. In addition, in situ ATR-FTIR and SFG measurements have been conducted when exposing the polyester-zinc/zinc oxide system to D<sub>2</sub>O. The exposure to D<sub>2</sub>O is observed to lead to an additional conversion of ester and carboxylic acid groups to carboxylate groups. The comparison of the SFG and ATR-FTIR measurements shows that this conversion occurs much slower at the polyester-zinc/zinc oxide interface than in the bulk of the polyester. Finally, the strengths and limitations as well as the complementarity of both techniques are discussed.</p>","is_dataset_classified":null,"base_score":3.6109179126442243,"endowment":3.6109179126442243,"datacite_reuse_total":0,"file_count":0,"downloads":0,"views":0,"has_version_chain":false,"is_dataset":false,"is_oa":false,"pmid":"21097893","pmcid":null,"openalex_id":"https://openalex.org/W3009788806","authors":[],"funders":[{"funder_name":"Nederlandse Organisatie voor Wetenschappelijk Onderzoek","grant_id":"F81.3.13509","title":null}],"total_grants":1,"fwci":2.1781,"citation_percentile":0.88019398,"influential_citations":0,"citation_trend":[{"year":2020,"count":4},{"year":2021,"count":2},{"year":2022,"count":5},{"year":2023,"count":8},{"year":2024,"count":5},{"year":2025,"count":6},{"year":2026,"count":6}],"oa_status":"hybrid","license":"cc-by-nc-nd","oa_locations":[{"url":"https://pubs.acs.org/doi/pdf/10.1021/acs.jpcc.9b10775","host_type":"journal"},{"url":"https://pubs.acs.org/doi/pdf/10.1021/acs.jpcc.9b10775","host_type":"HYBRID"},{"url":"https://pubs.acs.org/doi/pdf/10.1021/acs.jpcc.9b10775","host_type":"publisher"},{"url":"http://pubs.acs.org/doi/pdf/10.1021/acs.jpcc.9b10775","host_type":"publisher"},{"url":"https://doi.org/10.1021/acs.jpcc.9b10775","host_type":"journal"},{"url":"https://ir.amolf.nl/pub/10245","host_type":"repository"},{"url":"http://resolver.tudelft.nl/uuid:7ab2191d-9295-4d78-ada8-3054f8ebe078","host_type":"repository"},{"url":"https://ir.amolf.nl/pub/10245/16606OA.pdf","host_type":"repository"}],"fields_of_study":["Spectroscopy and Quantum Chemical Studies","Electrochemical Analysis and Applications","Analytical Chemistry and Sensors","Materials Science","Chemistry"],"mesh_terms":[],"keywords":["Attenuated total reflection","Fourier transform infrared spectroscopy","Zinc","Carboxylate","Chemistry","Infrared spectroscopy","Polyester","Analytical Chemistry (journal)","Spectroscopy","Infrared","Carboxylic acid","Polymer","Materials science","Polymer chemistry","Chemical engineering","Organic chemistry","Optics"],"sdg_mappings":[],"linked_datasets":[],"clinical_trials":[],"software_tools":[],"database_accessions":[],"source":"live","citation_network_status":"fetched"},"created_at":"2026-07-29T12:11:04.692696Z","pmid":null,"pmcid":null,"fwci":null,"citation_percentile":null,"influential_citations":0,"oa_status":null,"license":null,"views":0,"total_file_size_bytes":0,"version_count":0,"fair_f":null,"fair_a":null,"fair_i":null,"fair_r":null,"fair_zscore":null,"fair_rationale":null,"fair_model":null,"fair_agent_version":null,"fair_fulltext_source":null,"fair_has_llm":null,"fair_computed_at":null,"clinical_trials":[],"software_tools":[],"db_accessions":[],"linked_datasets":[],"topics":[]}