{"doi":"10.1021/acs.joc.2c01322","title":"One-Pot Assembly and Synthetic Applications of Geminal Acyl/Alkoxy Tetrasubstituted Allenes","abstract":"Polysubstituted allenes are useful synthetic intermediates in many applications, offering structural complexity, modularity, and their axial chirality in further transformations. While acyl and alkoxy-substituted allenes are known, there are currently few examples of allenes containing both functionalities and no reports of geminally substituted acyl/alkoxy allenes being isolated and characterized. Herein, we report the synthesis of tetrasubstituted allenes featuring a novel geminal acyl/alkoxy substitution. These unique \"push-pull\" allenes are bench-stable and exhibit interesting reactivity in several applications.","journal":"The Journal of Organic Chemistry","year":2022,"id":292086,"datarank":0.0,"base_score":0.0,"endowment":0.0,"self_citation_contribution":0.0,"citation_network_contribution":0.0,"self_endowment_contribution":0.0,"citer_contribution":0.0,"corpus_percentile":null,"corpus_rank":null,"citation_count":2,"citer_count":0,"citers_with_citation_signal":0,"citers_with_endowment":0,"datacite_reuse_total":0,"is_dataset":false,"is_dataset_confidence":0.939,"is_data_producer":false,"deposit_databanks":null,"is_oa":true,"file_count":0,"downloads":0,"has_version_chain":false,"published_date":"2022-01-01","fair_score":null,"fair_percentile":null,"algorithm_id":"datarank_citation_only_1hop_v6","ranking_scope":"data_only","authors":[{"id":976265,"name":"Garrett Toth-Williams","orcid":null,"position":1,"is_corresponding":false},{"id":975771,"name":"Anna Lo","orcid":"0000-0002-4489-3109","position":2,"is_corresponding":false},{"id":976266,"name":"Jeffrey W. Toman","orcid":null,"position":3,"is_corresponding":false},{"id":452547,"name":"James C. Fettinger","orcid":"0000-0002-6428-4909","position":4,"is_corresponding":false},{"id":332642,"name":"Jared T. Shaw","orcid":"0000-0001-5190-493X","position":5,"is_corresponding":false},{"id":921623,"name":"Benjamin D. Bergstrom","orcid":"0000-0003-2179-1334","position":0,"is_corresponding":true}],"reference_count":37,"raw_metadata":null,"created_at":"2026-07-19T00:30:42.221508Z","pmid":"36006876","pmcid":null,"fwci":null,"citation_percentile":null,"influential_citations":0,"oa_status":null,"license":null,"views":0,"total_file_size_bytes":0,"version_count":0,"fair_f":null,"fair_a":null,"fair_i":null,"fair_r":null,"fair_zscore":null,"fair_rationale":null,"fair_model":null,"fair_agent_version":null,"fair_fulltext_source":null,"fair_has_llm":null,"fair_computed_at":null,"clinical_trials":[],"software_tools":[],"db_accessions":[],"linked_datasets":[],"topics":[]}