{"doi":"10.1021/acs.cgd.2c00178","title":"Synthesis and Columnar Organization of Partially Fluorinated Dehydrobenz[18]annulenes","abstract":"Two diamond-shaped and partially fluorinated dehydrobenz[18]annulene macrocycles have been prepared through a one-pot synthesis relying on four-fold Sonogashira coupling. Single-crystal structures of these macrocycles show continuous columnar stacks held together by the fluoroarene–alkyne, arene–alkyne, fluoroarene–fluoroarene, and alkyne–alkyne [π···π] interactions instead of the expected fluoroarene–arene [π···π] interactions.","journal":"Crystal Growth & Design","year":2022,"id":289901,"datarank":0.0,"base_score":0.0,"endowment":0.0,"self_citation_contribution":0.0,"citation_network_contribution":0.0,"self_endowment_contribution":0.0,"citer_contribution":0.0,"corpus_percentile":null,"corpus_rank":null,"citation_count":4,"citer_count":0,"citers_with_citation_signal":0,"citers_with_endowment":0,"datacite_reuse_total":0,"is_dataset":false,"is_dataset_confidence":0.9488,"is_data_producer":false,"deposit_databanks":null,"is_oa":false,"file_count":0,"downloads":0,"has_version_chain":false,"published_date":"2022-01-01","fair_score":null,"fair_percentile":null,"algorithm_id":"datarank_citation_only_1hop_v6","ranking_scope":"data_only","authors":[{"id":481465,"name":"Lucas J. Karas","orcid":"0000-0001-7970-119X","position":1,"is_corresponding":false},{"id":971950,"name":"Xiqu Wang","orcid":"0000-0003-3869-4426","position":2,"is_corresponding":false},{"id":481466,"name":"Judy I. Wu","orcid":"0000-0003-0590-5290","position":3,"is_corresponding":false},{"id":328126,"name":"Ognjen Š. Miljanić","orcid":"0000-0002-7876-9034","position":4,"is_corresponding":false},{"id":971949,"name":"Sumitra Karki","orcid":"0000-0002-1062-3573","position":0,"is_corresponding":true}],"reference_count":60,"raw_metadata":null,"created_at":"2026-07-19T00:30:26.667578Z","pmid":null,"pmcid":null,"fwci":null,"citation_percentile":null,"influential_citations":0,"oa_status":null,"license":null,"views":0,"total_file_size_bytes":0,"version_count":0,"fair_f":null,"fair_a":null,"fair_i":null,"fair_r":null,"fair_zscore":null,"fair_rationale":null,"fair_model":null,"fair_agent_version":null,"fair_fulltext_source":null,"fair_has_llm":null,"fair_computed_at":null,"clinical_trials":[],"software_tools":[],"db_accessions":[],"linked_datasets":[],"topics":[]}