{"doi":"10.1002/smsc.202300110","title":"Engineering Supramolecular Hybrid Architectures with Directional Organofluorine Bonds","abstract":"Understanding how chemical modifications alter the atomic-scale organization of materials is of fundamental importance in materials engineering and the target of considerable efforts in computational prediction. Incorporating covalent and non-covalent interactions in designing crystals while \"piggybacking\" on the driving force of molecular self-assembly has augmented our efforts to understand the emergence of complex structures using directed synthesis. Here, we prepared microcrystalline powders of the silver 2-, 3-, and 4-fluorobenzenethiolates and resolved their structures by small molecule serial femtosecond X-ray crystallography (smSFX). These three compounds enable us to examine the emergence and role of supramolecular synthons in the crystal structures of three-dimensional metal-organic chalcogenolates (MOChas). The unique divergence in their optoelectronic, morphological, and structural behavior was assessed. The extent of C-H···F interactions and their influence on the structure and the observed trends in the thermal stability of the crystals were quantified through theoretical calculations and thermogravimetric analysis.","journal":"Small Science","year":2023,"id":364982,"datarank":0.0,"base_score":0.0,"endowment":0.0,"self_citation_contribution":0.0,"citation_network_contribution":0.0,"self_endowment_contribution":0.0,"citer_contribution":0.0,"corpus_percentile":null,"corpus_rank":null,"citation_count":7,"citer_count":0,"citers_with_citation_signal":0,"citers_with_endowment":0,"datacite_reuse_total":0,"is_dataset":false,"is_dataset_confidence":0.9534,"is_data_producer":false,"deposit_databanks":null,"is_oa":true,"file_count":0,"downloads":0,"has_version_chain":false,"published_date":"2023-01-01","fair_score":null,"fair_percentile":null,"algorithm_id":"datarank_citation_only_1hop_v6","ranking_scope":"data_only","authors":[{"id":306035,"name":"Daniel W. Paley⧓","orcid":"0000-0003-1161-5142","position":1,"is_corresponding":false},{"id":603630,"name":"Vanessa Oklejas","orcid":"0000-0001-5696-4720","position":2,"is_corresponding":false},{"id":773006,"name":"David Moreau","orcid":"0000-0002-3193-571X","position":3,"is_corresponding":false},{"id":756096,"name":"Elyse A. Schriber⧓","orcid":"0000-0002-8935-2955","position":4,"is_corresponding":false},{"id":1045120,"name":"Mariya Aleksich⧓","orcid":"0009-0004-2251-6013","position":5,"is_corresponding":false},{"id":1120087,"name":"Maggie C. Willson","orcid":"0009-0003-0188-1735","position":6,"is_corresponding":false},{"id":716893,"name":"Ichiro Inoue","orcid":"0009-0008-0423-1347","position":7,"is_corresponding":false},{"id":240881,"name":"Shigeki Owada","orcid":"0000-0002-1451-7612","position":8,"is_corresponding":false},{"id":240880,"name":"Kensuke Tono","orcid":"0000-0003-1218-3759","position":9,"is_corresponding":false},{"id":354606,"name":"Michihiro Sugahara","orcid":null,"position":10,"is_corresponding":false},{"id":1120088,"name":"Satomi Inaba‐Inoue","orcid":"0000-0002-6939-1324","position":11,"is_corresponding":false},{"id":282893,"name":"Andrew Aquila","orcid":"0000-0003-0358-2774","position":12,"is_corresponding":false},{"id":476922,"name":"Frédéric Poitevin","orcid":"0000-0002-3181-8652","position":13,"is_corresponding":false},{"id":715163,"name":"Johannes Blaschke","orcid":"0000-0002-6024-3990","position":14,"is_corresponding":false},{"id":458511,"name":"Stella Lisova","orcid":"0000-0002-6621-4285","position":15,"is_corresponding":false},{"id":282896,"name":"Mark S. Hunter","orcid":"0000-0002-0110-7075","position":16,"is_corresponding":false},{"id":271802,"name":"Raymond G. Sierra","orcid":"0000-0002-6253-8282","position":17,"is_corresponding":false},{"id":418258,"name":"José A. Gascón","orcid":"0000-0002-4176-9030","position":18,"is_corresponding":false},{"id":240887,"name":"Nicholas K. Sauter","orcid":"0000-0003-2786-6552","position":19,"is_corresponding":false},{"id":240886,"name":"Aaron S. Brewster","orcid":"0000-0002-0908-7822","position":20,"is_corresponding":false},{"id":756098,"name":"J. Nathan Hohman","orcid":"0000-0002-9777-6432","position":21,"is_corresponding":false},{"id":1045121,"name":"Patience A. Kotei","orcid":"0000-0001-6002-1645","position":0,"is_corresponding":true}],"reference_count":73,"raw_metadata":null,"created_at":"2026-07-19T01:14:41.218128Z","pmid":"39897162","pmcid":null,"fwci":null,"citation_percentile":null,"influential_citations":0,"oa_status":null,"license":null,"views":0,"total_file_size_bytes":0,"version_count":0,"fair_f":null,"fair_a":null,"fair_i":null,"fair_r":null,"fair_zscore":null,"fair_rationale":null,"fair_model":null,"fair_agent_version":null,"fair_fulltext_source":null,"fair_has_llm":null,"fair_computed_at":null,"clinical_trials":[],"software_tools":[],"db_accessions":[],"linked_datasets":[],"topics":[]}