{"doi":"10.1002/hc.20350","title":"Synthesis and characterization of oxime‐bearing hexakis(2‐formylphenoxy)‐phosphazene and its derivatives","abstract":"<jats:title>Abstract</jats:title><jats:p>Hexakis(2‐formylphenoxy)cyclotri‐phosphazene (<jats:bold>2</jats:bold>) was obtained from the reaction of hexachlorocylotriphosphazene (<jats:bold>1</jats:bold>) with 2‐hydroxy‐benzaldehyde. Hexakis(2‐[(hydroxyimino)methyl]‐phenoxy)cyclotriphosphazene <jats:bold>(3)</jats:bold> was synthesized from the reaction of <jats:bold>2</jats:bold> with hydroxlaminehydrochloride in pyridine. Hexasubstituted compounds <jats:bold>4, 5, 6, 8, 9</jats:bold>, and <jats:bold>10</jats:bold> were obtained from the reactions of <jats:bold>3</jats:bold> with methyl iodide, ethyl bromide, allyl bromide, propanoyl chloride, benzoyl chloride, and 4‐methoxybenzoyl chloride, respectively. Disubstituted product <jats:bold>7</jats:bold> was obtained from the reaction of <jats:bold>3</jats:bold> with chloroacetyl chloride. Pure and defined products could not be obtained from the reaction of <jats:bold>3</jats:bold> with acetyl chloride, benzyl chloride, and 2‐chlorobenzoyl chloride. The compounds were characterized by elemental analysis and IR, <jats:sup>1</jats:sup>H, <jats:sup>13</jats:sup>C, and <jats:sup>31</jats:sup>P NMR spectroscopy. © 2007 Wiley Periodicals, Inc. Heteroatom Chem 18:791–797, 2007; Published online in Wiley InterScience (<jats:ext-link xmlns:xlink=\"http://www.w3.org/1999/xlink\" xlink:href=\"http://www.interscience.wiley.com\">www.interscience.wiley.com</jats:ext-link>). DOI 10.1002/hc.20350</jats:p>","journal":"Heteroatom Chemistry","year":2007,"id":16546,"datarank":0.41697252906188975,"base_score":1.9459101490553132,"endowment":1.9459101490553132,"self_citation_contribution":0.29188652235829704,"citation_network_contribution":0.12508600670359268,"self_endowment_contribution":0.29188652235829704,"citer_contribution":0.12508600670359268,"corpus_percentile":null,"corpus_rank":null,"citation_count":6,"citer_count":2,"citers_with_citation_signal":2,"citers_with_endowment":2,"datacite_reuse_total":0,"is_dataset":false,"is_dataset_confidence":null,"is_data_producer":false,"deposit_databanks":null,"is_oa":false,"file_count":0,"downloads":0,"has_version_chain":false,"published_date":null,"fair_score":null,"fair_percentile":null,"algorithm_id":"datarank_citation_only_1hop_v6","ranking_scope":"data_only","authors":[{"id":118870,"name":"Erol Çil","orcid":null,"position":1,"is_corresponding":false},{"id":121723,"name":"Saliha Begeç","orcid":null,"position":2,"is_corresponding":false},{"id":118871,"name":"Mustafa Arslan","orcid":null,"position":3,"is_corresponding":false},{"id":121722,"name":"Orhan Pamukçi","orcid":null,"position":0,"is_corresponding":false}],"reference_count":0,"raw_metadata":{"has_enrichment":true,"base_score":1.9459101490553132,"endowment":1.9459101490553132,"datacite_reuse_total":0,"file_count":0,"downloads":0,"views":0,"has_version_chain":false,"is_dataset":false,"is_oa":false,"pmid":"21071399","pmcid":null,"openalex_id":"https://openalex.org/W1982394951","authors":[],"funders":[],"total_grants":0,"fwci":0.2873,"citation_percentile":0.58297258,"influential_citations":0,"citation_trend":[{"year":2012,"count":2},{"year":2018,"count":1},{"year":2020,"count":1},{"year":2025,"count":1}],"oa_status":"closed","license":"http://onlinelibrary.wiley.com/termsAndConditions#vor","oa_locations":[{"url":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fhc.20350","host_type":"publisher"},{"url":"https://onlinelibrary.wiley.com/doi/pdf/10.1002/hc.20350","host_type":"publisher"},{"url":"https://doi.org/10.1002/hc.20350","host_type":"journal"}],"fields_of_study":["Flame retardant materials and properties","Organophosphorus compounds synthesis","Synthesis of Organic Compounds","Chemistry"],"mesh_terms":[],"keywords":["Chemistry","Chloroacetyl chloride","Heteroatom","Phosphazene","Benzoyl chloride","Bromide","Chloride","Oxime","Pyridine","Iodide","Medicinal chemistry","Acetyl chloride","Ethyl chloroacetate","Organic chemistry","Ethyl iodide","Polymer chemistry","Benzaldehyde","Ring (chemistry)","Catalysis"],"sdg_mappings":[{"sdg_number":0,"sdg_label":"Clean water and sanitation"}],"linked_datasets":[],"clinical_trials":[],"software_tools":[],"database_accessions":[],"source":"live","citation_network_status":"fetched"},"created_at":"2026-06-02T10:55:30.769346Z","pmid":null,"pmcid":null,"fwci":null,"citation_percentile":null,"influential_citations":0,"oa_status":null,"license":null,"views":0,"total_file_size_bytes":0,"version_count":0,"fair_f":null,"fair_a":null,"fair_i":null,"fair_r":null,"fair_zscore":null,"fair_rationale":null,"fair_model":null,"fair_agent_version":null,"fair_fulltext_source":null,"fair_has_llm":null,"fair_computed_at":null,"clinical_trials":[],"software_tools":[],"db_accessions":[],"linked_datasets":[],"topics":[]}