{"doi":"10.1002/hc.1044","title":"Synthesis and metal transport ability of a new series of thiamacrocycles containing thiol and disulfide groups inside the ring","abstract":"<jats:title>Abstract</jats:title><jats:p>Synthetic methods for thiamacrocycles containing two thiol groups or a disulfide linkage and their abilities to effect single heavy‐metal‐ion transport across a liquid membrane were examined. High Ag<jats:sup>+</jats:sup> selectivity was accomplished by the thiol or disulfide hosts, although all the corresponding crown ether analogs bearing a disulfide group showed no Ag<jats:sup>+</jats:sup> selectivity. The difference of the transport preferences among the thiacrown ethers prepared here is considered to be reflected by the position and the number of the sulfur atoms ligating to Ag<jats:sup>+</jats:sup> and the cavity size of the hosts. © 2001 John Wiley &amp; Sons, Inc. Heteroatom Chem 12:276–281, 2001</jats:p>","journal":"Heteroatom Chemistry","year":2001,"id":23221,"datarank":0.3262049107478406,"base_score":1.9459101490553132,"endowment":1.9459101490553132,"self_citation_contribution":0.29188652235829704,"citation_network_contribution":0.03431838838954356,"self_endowment_contribution":0.29188652235829704,"citer_contribution":0.03431838838954356,"corpus_percentile":null,"corpus_rank":null,"citation_count":6,"citer_count":4,"citers_with_citation_signal":2,"citers_with_endowment":2,"datacite_reuse_total":0,"is_dataset":false,"is_dataset_confidence":null,"is_data_producer":false,"deposit_databanks":null,"is_oa":false,"file_count":0,"downloads":0,"has_version_chain":false,"published_date":null,"fair_score":null,"fair_percentile":null,"algorithm_id":"datarank_citation_only_1hop_v6","ranking_scope":"data_only","authors":[{"id":143324,"name":"Taizo Aoki","orcid":null,"position":1,"is_corresponding":false},{"id":143325,"name":"Tsutomu Haruyama","orcid":null,"position":2,"is_corresponding":false},{"id":143326,"name":"Toshinobu Shinnai","orcid":null,"position":3,"is_corresponding":false},{"id":143327,"name":"Hideaki Ohshiro","orcid":null,"position":4,"is_corresponding":false},{"id":143328,"name":"Toshiyuki Saiki","orcid":null,"position":5,"is_corresponding":false},{"id":143329,"name":"Yumihiko Yano","orcid":null,"position":6,"is_corresponding":false},{"id":143323,"name":"Tatsuya Nabeshima","orcid":null,"position":0,"is_corresponding":false}],"reference_count":0,"raw_metadata":{"has_enrichment":true,"base_score":1.9459101490553132,"endowment":1.9459101490553132,"datacite_reuse_total":0,"file_count":0,"downloads":0,"views":0,"has_version_chain":false,"is_dataset":false,"is_oa":false,"pmid":"24259432","pmcid":null,"openalex_id":"https://openalex.org/W2952613196","authors":[],"funders":[],"total_grants":0,"fwci":0.1378,"citation_percentile":0.52390414,"influential_citations":0,"citation_trend":[{"year":2014,"count":2}],"oa_status":"closed","license":"http://onlinelibrary.wiley.com/termsAndConditions#vor","oa_locations":[{"url":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fhc.1044","host_type":"publisher"},{"url":"https://onlinelibrary.wiley.com/doi/pdf/10.1002/hc.1044","host_type":"publisher"},{"url":"https://doi.org/10.1002/hc.1044","host_type":"journal"}],"fields_of_study":["Metal complexes synthesis and properties","DNA and Nucleic Acid Chemistry","Ferrocene Chemistry and Applications","Chemistry"],"mesh_terms":[],"keywords":["Chemistry","Heteroatom","Thiol","Disulfide bond","Disulfide Linkage","Selectivity","Ring (chemistry)","Sulfur","Ether","Metal","Polymer chemistry","Stereochemistry","Combinatorial chemistry","Organic chemistry","Cysteine","Biochemistry"],"sdg_mappings":[{"sdg_number":0,"sdg_label":"Clean water and sanitation"}],"linked_datasets":[],"clinical_trials":[],"software_tools":[],"database_accessions":[],"source":"live","citation_network_status":"fetched"},"created_at":"2026-06-07T18:41:47.322489Z","pmid":null,"pmcid":null,"fwci":null,"citation_percentile":null,"influential_citations":0,"oa_status":null,"license":null,"views":0,"total_file_size_bytes":0,"version_count":0,"fair_f":null,"fair_a":null,"fair_i":null,"fair_r":null,"fair_zscore":null,"fair_rationale":null,"fair_model":null,"fair_agent_version":null,"fair_fulltext_source":null,"fair_has_llm":null,"fair_computed_at":null,"clinical_trials":[],"software_tools":[],"db_accessions":[],"linked_datasets":[],"topics":[]}