{"doi":"10.1002/ejic.202300607","title":"[Ru<sub>3</sub>(CN)<sub>3</sub>(CO)<sub>9</sub>]<sup>3−</sup>:Building Block for Multimetallic Cages","abstract":"Abstract A cluster‐ligand is disclosed in the form of [Ru 3 (CN) 3 (CO) 9 ] 3− ([ 1 ] 3− ). Produced by simple reaction of [Ru 3 (CO) 12 ] with cyanide, [ 1 ] 3− serves as a precursor to a series of μ‐CN cages. When treated with [Ru 3 (CO) 12 ], it readily forms the prism [Ru 6 (μ‐CN) 3 (CO) 18 ] 3− . With 1.5 equiv. of [Cu(MeCN) 4 ] + [ 1 ] 3− reacts to give the expanded prism {Cu 3 [Ru 3 (μ‐CN) 3 (CO) 9 ] 2 } 3− , which features three two‐coordinate Cu(I) centers. Sources of Ni 2+ and Fe 2+ bind two equivalents of [ 1 ] 3− , giving the double cages {M[Ru 3 (μ‐CN) 3 (CO) 9 ] 2 } 4− (M=Ni, Fe) wherein the central metal is octahedral. The 1 : 1 reaction using [Fe(H 2 O) 6 ] 2+ gave the interpenetrated super‐tetrahedrane {Fe 4 (μ 4 ‐O)[Ru 3 (μ‐CN) 3 (CO) 9 ] 4 } 4− .","journal":"European Journal of Inorganic Chemistry","year":2023,"id":413393,"datarank":0.0,"base_score":0.0,"endowment":0.0,"self_citation_contribution":0.0,"citation_network_contribution":0.0,"self_endowment_contribution":0.0,"citer_contribution":0.0,"corpus_percentile":null,"corpus_rank":null,"citation_count":0,"citer_count":0,"citers_with_citation_signal":0,"citers_with_endowment":0,"datacite_reuse_total":0,"is_dataset":false,"is_dataset_confidence":0.948,"is_data_producer":false,"deposit_databanks":null,"is_oa":true,"file_count":0,"downloads":0,"has_version_chain":false,"published_date":"2023-01-01","fair_score":null,"fair_percentile":null,"algorithm_id":"datarank_citation_only_1hop_v6","ranking_scope":"data_only","authors":[{"id":1113354,"name":"Yu Zhang","orcid":"0000-0001-8948-1434","position":1,"is_corresponding":false},{"id":378738,"name":"Toby J. Woods","orcid":"0000-0002-1737-811X","position":2,"is_corresponding":false},{"id":225328,"name":"Thomas B. Rauchfuss","orcid":"0000-0003-2547-5128","position":3,"is_corresponding":false},{"id":1152005,"name":"Ping Wang","orcid":"0000-0002-5015-0985","position":0,"is_corresponding":true}],"reference_count":18,"raw_metadata":null,"created_at":"2026-07-19T01:21:57.641539Z","pmid":"38983975","pmcid":null,"fwci":null,"citation_percentile":null,"influential_citations":0,"oa_status":null,"license":null,"views":0,"total_file_size_bytes":0,"version_count":0,"fair_f":null,"fair_a":null,"fair_i":null,"fair_r":null,"fair_zscore":null,"fair_rationale":null,"fair_model":null,"fair_agent_version":null,"fair_fulltext_source":null,"fair_has_llm":null,"fair_computed_at":null,"clinical_trials":[],"software_tools":[],"db_accessions":[],"linked_datasets":[],"topics":[]}