{"doi":"10.1002/ejic.202000736","title":"Reactions of [Fe<sub>6</sub>C(CO)<sub>14</sub>(S)]<sup>2</sup><sup>–</sup>: Cluster Growth, Redox, Sulfiding","abstract":"Redox reactions, substitutions, and metalations are reported for the iron carbido sulfide [Fe 6 C(CO) 14 (S)] 2– ([ 1 ] 2– ). Dianion [ 1 ] 2– oxidized to [Fe 6 C(CO) 16 (S)] 0 ([ 2 ] 0 ) upon treatment with of [Fe(C 5 H 5 ) 2 ]BF 4 or HBF 4 (H 2 formation) under an atmosphere of CO. Reaction of [ 2 ] 0 with t BuNC gave [Fe 6 C(S)(CO) 13 ( t BuNC) 5 ], consisting of Fe 5 C(CO) 13 and [Fe( t BuNC) 5 ] 2+ subunits linked by a µ 3 ‐S 2– . The Fe 7 CS cluster [Fe 7 C(CO) 17 (S)] 2– formed upon treatment of (Ph 4 P) 2 [ 1 ] with Fe(benzylideneacetone)(CO) 3 . The Fe 7 species is an edge‐fused cluster with [Fe 6 C(CO) 10 (µ‐CO) 4 ] and Fe(CO) 3 subunits joined by µ 3 ‐S and two Fe–Fe bonds. The analogous reaction using Mo(CO) 4 (norbornadiene) gave [MoFe 6 C(CO) 18 (S)] 2– . In this cluster, the Mo center is located in the octahedral subunit. Treatment of [ 1 ] 2– with SO 2 afforded [Fe 6 C(S)(SO 2 )(CO) 13 ] 2– . This cluster features an Fe 6 C core decorated with µ 3 ‐S and µ 2 ‐SO 2 ligands. These experiments were undertaken in an effort to connect organometallic clusters to FeMoco.","journal":"European Journal of Inorganic Chemistry","year":2020,"id":71703,"datarank":0.0,"base_score":0.0,"endowment":0.0,"self_citation_contribution":0.0,"citation_network_contribution":0.0,"self_endowment_contribution":0.0,"citer_contribution":0.0,"corpus_percentile":null,"corpus_rank":null,"citation_count":17,"citer_count":0,"citers_with_citation_signal":0,"citers_with_endowment":0,"datacite_reuse_total":0,"is_dataset":false,"is_dataset_confidence":0.9533,"is_data_producer":false,"deposit_databanks":null,"is_oa":true,"file_count":0,"downloads":0,"has_version_chain":false,"published_date":"2020-01-01","fair_score":null,"fair_percentile":null,"algorithm_id":"datarank_citation_only_1hop_v6","ranking_scope":"data_only","authors":[{"id":378738,"name":"Toby J. Woods","orcid":"0000-0002-1737-811X","position":1,"is_corresponding":false},{"id":225328,"name":"Thomas B. Rauchfuss","orcid":"0000-0003-2547-5128","position":2,"is_corresponding":false},{"id":378737,"name":"Liang Liu","orcid":"0000-0001-7025-5330","position":0,"is_corresponding":true}],"reference_count":27,"raw_metadata":null,"created_at":"2026-07-18T21:44:25.469842Z","pmid":"33883972","pmcid":null,"fwci":null,"citation_percentile":null,"influential_citations":0,"oa_status":null,"license":null,"views":0,"total_file_size_bytes":0,"version_count":0,"fair_f":null,"fair_a":null,"fair_i":null,"fair_r":null,"fair_zscore":null,"fair_rationale":null,"fair_model":null,"fair_agent_version":null,"fair_fulltext_source":null,"fair_has_llm":null,"fair_computed_at":null,"clinical_trials":[],"software_tools":[],"db_accessions":[],"linked_datasets":[],"topics":[]}