{"doi":"10.1002/ejic.201901335","title":"Evaluating Metal Ion Identity on Catalytic Silylation of Dinitrogen Using a Series of Trimetallic Complexes","abstract":"We report catalytic silylation of dinitrogen to tris(trimethylsilyl)amine by a series of trinuclear first row transition metal complexes (M = Cr, Mn, Fe, Co, Ni) housed in our tris(β‐diketiminate) cyclophane ( L 3– ). Yields are expectedly dependent on metal ion type ranging from 14 to 199 equiv. NH 4 + /complex after protonolysis for the Mn to Co congeners, respectively. For the series of complexes, the observed trend for the number of turnovers as a function of metal ion type is Co > Fe > Cr > Ni > Mn, consistent with prior reports of greater efficacy of Co over Fe in other ligand systems for this reaction.","journal":"European Journal of Inorganic Chemistry","year":2020,"id":91329,"datarank":0.0,"base_score":0.0,"endowment":0.0,"self_citation_contribution":0.0,"citation_network_contribution":0.0,"self_endowment_contribution":0.0,"citer_contribution":0.0,"corpus_percentile":null,"corpus_rank":null,"citation_count":45,"citer_count":0,"citers_with_citation_signal":0,"citers_with_endowment":0,"datacite_reuse_total":0,"is_dataset":false,"is_dataset_confidence":0.963,"is_data_producer":false,"deposit_databanks":null,"is_oa":true,"file_count":0,"downloads":0,"has_version_chain":false,"published_date":"2020-01-01","fair_score":null,"fair_percentile":null,"algorithm_id":"datarank_citation_only_1hop_v6","ranking_scope":"data_only","authors":[{"id":457345,"name":"Brian J. Knight","orcid":"0000-0001-6702-1568","position":1,"is_corresponding":false},{"id":457346,"name":"Vincent J. Catalano","orcid":"0000-0003-2151-2892","position":2,"is_corresponding":false},{"id":457347,"name":"Leslie J. Murray","orcid":"0000-0002-1568-958X","position":3,"is_corresponding":false},{"id":457344,"name":"Mary C. Eaton","orcid":"0000-0003-1515-0231","position":0,"is_corresponding":true}],"reference_count":61,"raw_metadata":null,"created_at":"2026-07-18T22:28:45.409789Z","pmid":"33071629","pmcid":null,"fwci":null,"citation_percentile":null,"influential_citations":0,"oa_status":null,"license":null,"views":0,"total_file_size_bytes":0,"version_count":0,"fair_f":null,"fair_a":null,"fair_i":null,"fair_r":null,"fair_zscore":null,"fair_rationale":null,"fair_model":null,"fair_agent_version":null,"fair_fulltext_source":null,"fair_has_llm":null,"fair_computed_at":null,"clinical_trials":[],"software_tools":[],"db_accessions":[],"linked_datasets":[],"topics":[]}