{"doi":"10.1002/anie.202306511","title":"Copper‐Phosphido Catalysis: Enantioselective Addition of Phosphines to Cyclopropenes**","abstract":"Abstract We describe a copper catalyst that promotes the addition of phosphines to cyclopropenes at ambient temperature. A range of cyclopropylphosphines bearing different steric and electronic properties can now be accessed in high yields and enantioselectivities. Enrichment of phosphorus stereocenters is also demonstrated via a Dynamic Kinetic Asymmetric Transformation (DyKAT) process. A combined experimental and theoretical mechanistic study supports an elementary step featuring insertion of a Cu I ‐phosphido into a carbon‐carbon double bond. Density functional theory calculations reveal migratory insertion as the rate‐ and stereo‐determining step, followed by a syn‐ protodemetalation.","journal":"Angewandte Chemie International Edition","year":2023,"id":321225,"datarank":0.0,"base_score":0.0,"endowment":0.0,"self_citation_contribution":0.0,"citation_network_contribution":0.0,"self_endowment_contribution":0.0,"citer_contribution":0.0,"corpus_percentile":null,"corpus_rank":null,"citation_count":45,"citer_count":0,"citers_with_citation_signal":0,"citers_with_endowment":0,"datacite_reuse_total":0,"is_dataset":false,"is_dataset_confidence":0.9456,"is_data_producer":false,"deposit_databanks":null,"is_oa":true,"file_count":0,"downloads":0,"has_version_chain":false,"published_date":"2023-01-01","fair_score":null,"fair_percentile":null,"algorithm_id":"datarank_citation_only_1hop_v6","ranking_scope":"data_only","authors":[{"id":589901,"name":"Xintong Hou","orcid":null,"position":1,"is_corresponding":false},{"id":890217,"name":"Stephanie A. Corio","orcid":"0000-0001-9029-3895","position":2,"is_corresponding":false},{"id":1033190,"name":"Lindsey M. Weissman","orcid":"0000-0003-4437-9991","position":3,"is_corresponding":false},{"id":589747,"name":"Vy M. Dong","orcid":"0000-0002-8099-1048","position":4,"is_corresponding":false},{"id":651913,"name":"Jennifer S. Hirschi","orcid":"0000-0002-3470-0561","position":5,"is_corresponding":false},{"id":1033191,"name":"Shao‐Zhen Nie","orcid":"0000-0003-2227-710X","position":6,"is_corresponding":false},{"id":1033902,"name":"Brian S. Daniels","orcid":null,"position":0,"is_corresponding":true}],"reference_count":127,"raw_metadata":null,"created_at":"2026-07-19T01:07:32.611759Z","pmid":"37332088","pmcid":null,"fwci":null,"citation_percentile":null,"influential_citations":0,"oa_status":null,"license":null,"views":0,"total_file_size_bytes":0,"version_count":0,"fair_f":null,"fair_a":null,"fair_i":null,"fair_r":null,"fair_zscore":null,"fair_rationale":null,"fair_model":null,"fair_agent_version":null,"fair_fulltext_source":null,"fair_has_llm":null,"fair_computed_at":null,"clinical_trials":[],"software_tools":[],"db_accessions":[],"linked_datasets":[],"topics":[]}