{"doi":"10.1002/anie.202211794","title":"Structurally Diverse Bench‐Stable Nickel(0) Pre‐Catalysts: A Practical Toolkit for In Situ Ligation Protocols**","abstract":"A flurry of recent research has centered on harnessing the power of nickel catalysis in organic synthesis. These efforts have been bolstered by contemporaneous development of well-defined nickel (pre)catalysts with diverse structure and reactivity. In this report, we present ten different bench-stable, 18-electron, formally zero-valent nickel-olefin complexes that are competent pre-catalysts in various reactions. Our investigation includes preparations of novel, bench-stable Ni(COD)(L) complexes (COD=1,5-cyclooctadiene), in which L=quinone, cyclopentadienone, thiophene-S-oxide, and fulvene. Characterization by NMR, IR, single-crystal X-ray diffraction, cyclic voltammetry, thermogravimetric analysis, and natural bond orbital analysis sheds light on the structure, bonding, and properties of these complexes. Applications in an assortment of nickel-catalyzed reactions underscore the complementary nature of the different pre-catalysts within this toolkit.","journal":"Angewandte Chemie International Edition","year":2022,"id":239167,"datarank":0.0,"base_score":0.0,"endowment":0.0,"self_citation_contribution":0.0,"citation_network_contribution":0.0,"self_endowment_contribution":0.0,"citer_contribution":0.0,"corpus_percentile":null,"corpus_rank":null,"citation_count":51,"citer_count":0,"citers_with_citation_signal":0,"citers_with_endowment":0,"datacite_reuse_total":0,"is_dataset":false,"is_dataset_confidence":0.9445,"is_data_producer":false,"deposit_databanks":null,"is_oa":true,"file_count":0,"downloads":0,"has_version_chain":false,"published_date":"2022-01-01","fair_score":null,"fair_percentile":null,"algorithm_id":"datarank_citation_only_1hop_v6","ranking_scope":"data_only","authors":[{"id":864474,"name":"Nana Kim","orcid":"0000-0001-6777-2193","position":1,"is_corresponding":false},{"id":350596,"name":"Camille Rubel","orcid":"0000-0003-0861-6590","position":2,"is_corresponding":false},{"id":853258,"name":"Xiangyu Wu","orcid":"0000-0003-1169-1997","position":3,"is_corresponding":false},{"id":588164,"name":"Taeho Kang","orcid":"0000-0003-4549-262X","position":4,"is_corresponding":false},{"id":810006,"name":"Tanner C. Jankins","orcid":"0000-0002-4408-9751","position":5,"is_corresponding":false},{"id":492204,"name":"Zi‐Qi Li","orcid":"0000-0002-1353-3004","position":6,"is_corresponding":false},{"id":864475,"name":"Matthew V. Joannou","orcid":"0000-0002-0079-7107","position":7,"is_corresponding":false},{"id":864476,"name":"Sloan Ayers","orcid":"0000-0003-3562-1846","position":8,"is_corresponding":false},{"id":810007,"name":"Milan Gembický","orcid":"0000-0002-3898-1612","position":9,"is_corresponding":false},{"id":503624,"name":"Jake Bailey","orcid":"0000-0002-4659-8189","position":10,"is_corresponding":false},{"id":346187,"name":"Emily Sturgell","orcid":null,"position":11,"is_corresponding":false},{"id":346186,"name":"Brittany B. Sanchez","orcid":null,"position":12,"is_corresponding":false},{"id":321506,"name":"Jason S. Chen","orcid":"0000-0002-7341-5763","position":13,"is_corresponding":false},{"id":823504,"name":"Song Lin","orcid":"0000-0002-8880-6476","position":14,"is_corresponding":false},{"id":321505,"name":"Martin D. Eastgate","orcid":"0000-0002-6487-3121","position":15,"is_corresponding":false},{"id":321501,"name":"Steven R. Wisniewski","orcid":"0000-0001-6035-4394","position":16,"is_corresponding":false},{"id":315493,"name":"Keary M. Engle","orcid":"0000-0003-2767-6556","position":17,"is_corresponding":false},{"id":492206,"name":"Van Tran","orcid":"0000-0001-7878-1327","position":0,"is_corresponding":true}],"reference_count":59,"raw_metadata":null,"created_at":"2026-07-19T00:22:36.865157Z","pmid":"36524997","pmcid":null,"fwci":null,"citation_percentile":null,"influential_citations":0,"oa_status":null,"license":null,"views":0,"total_file_size_bytes":0,"version_count":0,"fair_f":null,"fair_a":null,"fair_i":null,"fair_r":null,"fair_zscore":null,"fair_rationale":null,"fair_model":null,"fair_agent_version":null,"fair_fulltext_source":null,"fair_has_llm":null,"fair_computed_at":null,"clinical_trials":[],"software_tools":[],"db_accessions":[],"linked_datasets":[],"topics":[]}