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This material was synthesized using an in situ method as a gel, under which imine hydrolysis and metalation reactions are coupled. Local defects formed in situ within imine‐linked 2D‐COF materials are highly reactive towards Pd metalation, resulting in active materials for Suzuki–Miyaura cross‐coupling reactions.</jats:p>","journal":"Angewandte Chemie International Edition","year":2020,"id":662235,"datarank":0.6830815337400812,"base_score":4.553876891600541,"endowment":4.553876891600541,"self_citation_contribution":0.6830815337400812,"citation_network_contribution":0.0,"self_endowment_contribution":0.6830815337400812,"citer_contribution":0.0,"corpus_percentile":null,"corpus_rank":null,"citation_count":94,"citer_count":0,"citers_with_citation_signal":0,"citers_with_endowment":0,"datacite_reuse_total":0,"is_dataset":false,"is_dataset_confidence":null,"is_data_producer":false,"deposit_databanks":null,"is_oa":false,"file_count":0,"downloads":0,"has_version_chain":false,"published_date":null,"fair_score":null,"fair_percentile":null,"algorithm_id":"datarank_citation_only_1hop_v6","ranking_scope":"data_only","authors":[{"id":1728802,"name":"Andreas Mavrandonakis","orcid":"0000-0002-5053-8154","position":1,"is_corresponding":false},{"id":1728803,"name":"Pablo Albacete","orcid":null,"position":2,"is_corresponding":false},{"id":1728804,"name":"Alicia Vega","orcid":null,"position":3,"is_corresponding":false},{"id":1728805,"name":"Valérie Briois","orcid":null,"position":4,"is_corresponding":false},{"id":1728806,"name":"Félix Zamora","orcid":"0000-0001-7529-5120","position":5,"is_corresponding":false},{"id":1728807,"name":"Ana E. 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