{"doi":"10.1002/anie.202002364","title":"Synthesis of a “Masked” Terminal Zinc Sulfide and Its Reactivity with Brønsted and Lewis Acids","abstract":"Abstract The “masked” terminal Zn sulfide, [K(2.2.2‐cryptand)][ Me LZn(S)] ( 2 ) ( Me L={(2,6‐ i Pr 2 C 6 H 3 )NC(Me)} 2 CH), was isolated via reaction of [ Me LZnSCPh 3 ] ( 1 ) with 2.3 equivalents of KC 8 in THF, in the presence of 2.2.2‐cryptand, at −78 °C. Complex 2 reacts readily with PhCCH and N 2 O to form [K(2.2.2‐cryptand)][ Me LZn(SH)(CCPh)] ( 4 ) and [K(2.2.2‐cryptand)][ Me LZn(SNNO)] ( 5 ), respectively, displaying both Brønsted and Lewis basicity. In addition, the electronic structure of 2 was examined computationally and compared with the previously reported Ni congener, [K(2.2.2‐cryptand)][ tBu LNi(S)] ( tBu L={(2,6‐ i Pr 2 C 6 H 3 )NC( t Bu)} 2 CH).","journal":"Angewandte Chemie International Edition","year":2020,"id":88059,"datarank":0.0,"base_score":0.0,"endowment":0.0,"self_citation_contribution":0.0,"citation_network_contribution":0.0,"self_endowment_contribution":0.0,"citer_contribution":0.0,"corpus_percentile":null,"corpus_rank":null,"citation_count":10,"citer_count":0,"citers_with_citation_signal":0,"citers_with_endowment":0,"datacite_reuse_total":0,"is_dataset":false,"is_dataset_confidence":0.953,"is_data_producer":false,"deposit_databanks":null,"is_oa":true,"file_count":0,"downloads":0,"has_version_chain":false,"published_date":"2020-01-01","fair_score":null,"fair_percentile":null,"algorithm_id":"datarank_citation_only_1hop_v6","ranking_scope":"data_only","authors":[{"id":447028,"name":"Guang Wu","orcid":"0000-0001-7257-6648","position":1,"is_corresponding":false},{"id":447029,"name":"Nikolas Kaltsoyannis","orcid":"0000-0003-0293-5742","position":2,"is_corresponding":false},{"id":422733,"name":"Trevor W. Hayton","orcid":"0000-0003-4370-1424","position":3,"is_corresponding":false},{"id":447027,"name":"Miguel Á. Baeza Cinco","orcid":"0000-0003-2517-4077","position":0,"is_corresponding":true}],"reference_count":56,"raw_metadata":null,"created_at":"2026-07-18T22:00:56.736935Z","pmid":"32196886","pmcid":null,"fwci":null,"citation_percentile":null,"influential_citations":0,"oa_status":null,"license":null,"views":0,"total_file_size_bytes":0,"version_count":0,"fair_f":null,"fair_a":null,"fair_i":null,"fair_r":null,"fair_zscore":null,"fair_rationale":null,"fair_model":null,"fair_agent_version":null,"fair_fulltext_source":null,"fair_has_llm":null,"fair_computed_at":null,"clinical_trials":[],"software_tools":[],"db_accessions":[],"linked_datasets":[],"topics":[]}