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The preliminary mechanistic studies revealed that: 1) an SET process between [Ru(phen)<jats:sub>3</jats:sub>]<jats:sup>2+</jats:sup>* and aniline play an important role; 2) O<jats:sub>2</jats:sub> activation might be the rate‐determining step; and 3) the decarboxylation step is an irreversible and fast process.</jats:p>","journal":"Angewandte Chemie International Edition","year":2014,"id":673161,"datarank":0.9150478428030098,"base_score":6.100318952020064,"endowment":6.100318952020064,"self_citation_contribution":0.9150478428030098,"citation_network_contribution":0.0,"self_endowment_contribution":0.9150478428030098,"citer_contribution":0.0,"corpus_percentile":null,"corpus_rank":null,"citation_count":445,"citer_count":0,"citers_with_citation_signal":0,"citers_with_endowment":0,"datacite_reuse_total":0,"is_dataset":false,"is_dataset_confidence":null,"is_data_producer":false,"deposit_databanks":null,"is_oa":false,"file_count":0,"downloads":0,"has_version_chain":false,"published_date":null,"fair_score":null,"fair_percentile":null,"algorithm_id":"datarank_citation_only_1hop_v6","ranking_scope":"data_only","authors":[{"id":416396,"name":"Qiang Liu","orcid":"0000-0003-1229-7908","position":1,"is_corresponding":false},{"id":1487771,"name":"Hong Yi","orcid":"0000-0002-7923-4971","position":2,"is_corresponding":false},{"id":1758789,"name":"Chu Qin","orcid":null,"position":3,"is_corresponding":false},{"id":1758790,"name":"Ruopeng Bai","orcid":"0000-0002-1097-8526","position":4,"is_corresponding":false},{"id":181949,"name":"Xiaotian Qi","orcid":"0000-0001-5420-5958","position":5,"is_corresponding":false},{"id":956914,"name":"Yu Lan","orcid":"0000-0003-0373-1944","position":6,"is_corresponding":false},{"id":1558594,"name":"Aiwen Lei","orcid":null,"position":7,"is_corresponding":false},{"id":831265,"name":"Jie Liu","orcid":"0000-0002-2373-7190","position":0,"is_corresponding":false}],"reference_count":0,"raw_metadata":{"has_enrichment":true,"resolved":true,"title":"Visible‐Light‐Mediated Decarboxylation/Oxidative Amidation of α‐Keto Acids with Amines under Mild Reaction Conditions Using O<sub>2</sub>","abstract":"<jats:title>Abstract</jats:title><jats:p>Photochemistry has ushered in a new era in the development of chemistry, and photoredox catalysis has become a hot topic, especially over the last five years, with the combination of visible‐light photoredox catalysis and radical reactions. A novel, simple, and efficient radical oxidative decarboxylative coupling with the assistant of the photocatalyst [Ru(phen)<jats:sub>3</jats:sub>]Cl<jats:sub>2</jats:sub> is described. Various functional groups are well‐tolerated in this reaction and thus provides a new approach to developing advanced methods for aerobic oxidative decarboxylation. The preliminary mechanistic studies revealed that: 1) an SET process between [Ru(phen)<jats:sub>3</jats:sub>]<jats:sup>2+</jats:sup>* and aniline play an important role; 2) O<jats:sub>2</jats:sub> activation might be the rate‐determining step; and 3) the decarboxylation step is an irreversible and fast process.</jats:p>","is_dataset_classified":null,"base_score":6.100318952020064,"endowment":6.100318952020064,"datacite_reuse_total":0,"file_count":0,"downloads":0,"views":0,"has_version_chain":false,"is_dataset":false,"is_oa":false,"pmid":"24272969","pmcid":null,"openalex_id":"https://openalex.org/W2159551189","authors":[],"funders":[],"total_grants":0,"fwci":20.7905,"citation_percentile":0.99777893,"influential_citations":0,"citation_trend":[{"year":2014,"count":23},{"year":2015,"count":53},{"year":2016,"count":55},{"year":2017,"count":45},{"year":2018,"count":42},{"year":2019,"count":30},{"year":2020,"count":25},{"year":2021,"count":36},{"year":2022,"count":33},{"year":2023,"count":28},{"year":2024,"count":34},{"year":2025,"count":23},{"year":2026,"count":17}],"oa_status":"closed","license":"http://onlinelibrary.wiley.com/termsAndConditions#vor","oa_locations":[{"url":"https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fanie.201308614","host_type":"publisher"},{"url":"https://onlinelibrary.wiley.com/doi/pdf/10.1002/anie.201308614","host_type":"publisher"},{"url":"https://doi.org/10.1002/anie.201308614","host_type":"journal"},{"url":"https://pubmed.ncbi.nlm.nih.gov/24272969","host_type":"repository"}],"fields_of_study":["Radical Photochemical Reactions","Catalytic C–H Functionalization Methods","Sulfur-Based Synthesis Techniques"],"mesh_terms":["Amides","Amines","Aniline Compounds","Catalysis","Decarboxylation","Hydrocarbons, Chlorinated","Keto Acids","Light","Oxidation-Reduction","Oxygen","Photochemistry","Ruthenium","Molecular Structure"],"keywords":["Decarboxylation","Oxidative decarboxylation","Photoredox catalysis","Chemistry","Aniline","Photochemistry","Catalysis","Oxidative phosphorylation","Oxidative coupling of methane","Photocatalysis","Visible spectrum","Aniline Compounds","Combinatorial chemistry","Organic chemistry","Materials science","Biochemistry","Reaction mechanism","Amides","Synthetic Methods","Computational Chemistry"],"sdg_mappings":[],"linked_datasets":[],"clinical_trials":[],"software_tools":[],"database_accessions":[],"source":"live","citation_network_status":"fetched"},"created_at":"2026-08-16T12:33:53.913790Z","pmid":null,"pmcid":null,"fwci":null,"citation_percentile":null,"influential_citations":0,"oa_status":null,"license":null,"views":0,"total_file_size_bytes":0,"version_count":0,"fair_f":null,"fair_a":null,"fair_i":null,"fair_r":null,"fair_zscore":null,"fair_rationale":null,"fair_model":null,"fair_agent_version":null,"fair_fulltext_source":null,"fair_has_llm":null,"fair_computed_at":null,"clinical_trials":[],"software_tools":[],"db_accessions":[],"linked_datasets":[],"topics":[]}