{"doi":"10.1002/ange.202214153","title":"A Sterically Tuned Directing Auxiliary Promotes Catalytic 1,2‐Carbofluorination of Alkenyl Carbonyl Compounds**","abstract":"Abstract The site‐selective palladium‐catalyzed three‐component coupling of unactivated alkenyl carbonyl compounds, aryl‐ or alkenylboronic acids, and N ‐fluorobenzenesulfonimide is described herein. Tuning of the steric environment on the bidentate directing auxiliary enhances regioselectivity and facilitates challenging C(sp 3 )−F reductive elimination from a Pd IV intermediate to afford 1,2‐carbofluorination products in moderate to good yields.","journal":"Angewandte Chemie","year":2022,"id":280071,"datarank":0.0,"base_score":0.0,"endowment":0.0,"self_citation_contribution":0.0,"citation_network_contribution":0.0,"self_endowment_contribution":0.0,"citer_contribution":0.0,"corpus_percentile":null,"corpus_rank":null,"citation_count":1,"citer_count":0,"citers_with_citation_signal":0,"citers_with_endowment":0,"datacite_reuse_total":0,"is_dataset":false,"is_dataset_confidence":0.9408,"is_data_producer":false,"deposit_databanks":null,"is_oa":true,"file_count":0,"downloads":0,"has_version_chain":false,"published_date":"2022-01-01","fair_score":null,"fair_percentile":null,"algorithm_id":"datarank_citation_only_1hop_v6","ranking_scope":"data_only","authors":[{"id":816516,"name":"Lucas J. Oxtoby","orcid":null,"position":1,"is_corresponding":false},{"id":954115,"name":"Juntao Sun","orcid":"0000-0001-8973-1376","position":2,"is_corresponding":false},{"id":492204,"name":"Zi‐Qi Li","orcid":"0000-0002-1353-3004","position":3,"is_corresponding":false},{"id":864474,"name":"Nana Kim","orcid":"0000-0001-6777-2193","position":4,"is_corresponding":false},{"id":954125,"name":"Geraint H. M. Davies","orcid":"0000-0002-5986-0756","position":5,"is_corresponding":false},{"id":315493,"name":"Keary M. Engle","orcid":"0000-0003-2767-6556","position":6,"is_corresponding":false},{"id":492207,"name":"Zhonglin Liu","orcid":"0000-0001-6004-7722","position":0,"is_corresponding":true}],"reference_count":48,"raw_metadata":null,"created_at":"2026-07-19T00:28:59.341002Z","pmid":null,"pmcid":null,"fwci":null,"citation_percentile":null,"influential_citations":0,"oa_status":null,"license":null,"views":0,"total_file_size_bytes":0,"version_count":0,"fair_f":null,"fair_a":null,"fair_i":null,"fair_r":null,"fair_zscore":null,"fair_rationale":null,"fair_model":null,"fair_agent_version":null,"fair_fulltext_source":null,"fair_has_llm":null,"fair_computed_at":null,"clinical_trials":[],"software_tools":[],"db_accessions":[],"linked_datasets":[],"topics":[]}