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With the use of 2–5 mol % of Pd catalyst and 4–10 mol % of P‐chirogenic diaminophosphine oxides, asymmetric allylic alkylation of γ‐acetoxy‐α,β‐unsaturated carbonyl compounds with various prochiral nucleophiles derived from cyclic β‐keto esters proceeded in the presence of Zn(OAc)<jats:sub>2</jats:sub>, providing the corresponding products with an all‐carbon quaternary stereocenter in up to 95% ee.</jats:p>","journal":"Advanced Synthesis &amp; Catalysis","year":2005,"id":687203,"datarank":0.5897738449086489,"base_score":3.9318256327243257,"endowment":3.9318256327243257,"self_citation_contribution":0.5897738449086489,"citation_network_contribution":0.0,"self_endowment_contribution":0.5897738449086489,"citer_contribution":0.0,"corpus_percentile":null,"corpus_rank":null,"citation_count":50,"citer_count":0,"citers_with_citation_signal":0,"citers_with_endowment":0,"datacite_reuse_total":0,"is_dataset":false,"is_dataset_confidence":null,"is_data_producer":false,"deposit_databanks":null,"is_oa":false,"file_count":0,"downloads":0,"has_version_chain":false,"published_date":null,"fair_score":null,"fair_percentile":null,"algorithm_id":"datarank_citation_only_1hop_v6","ranking_scope":"data_only","authors":[{"id":1795299,"name":"Tomoaki Fukuda","orcid":null,"position":1,"is_corresponding":false},{"id":1779398,"name":"Takayoshi Matsumoto","orcid":null,"position":2,"is_corresponding":false},{"id":1795302,"name":"Tsukasa Hitomi","orcid":null,"position":3,"is_corresponding":false},{"id":1779399,"name":"Yasumasa Hamada","orcid":null,"position":4,"is_corresponding":false},{"id":1779396,"name":"Tetsuhiro Nemoto","orcid":null,"position":0,"is_corresponding":false}],"reference_count":0,"raw_metadata":{"has_enrichment":true,"resolved":true,"title":"Enantioselective Construction of All‐Carbon Quaternary Stereocenters Using Palladium‐Catalyzed Asymmetric Allylic Alkylation of γ‐Acetoxy‐α,β‐unsaturated Carbonyl Compounds","abstract":"<jats:title>Abstract</jats:title><jats:p>We have successfully demonstrated that γ‐acetoxy‐α,β‐unsaturated carbonyl compounds are useful starting materials for Pd‐catalyzed asymmetric allylic alkylation to construct all‐carbon quaternary stereocenters. 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